Pressure response of the higher fullerene C84 studied by Raman and X-ray scattering

S. Assimopoulos; K. P. Meletov; G. A. Kourouklis; I. Margiolaki; S. Margadonna; K. Prassides; T. J.S. Dennis; H. Shinohara

doi:10.1080/08957950211373

Pressure response of the higher fullerene C₈₄ studied by Raman and X-ray scattering

S. Assimopoulos^*, K. P. Meletov, G. A. Kourouklis, I. Margiolaki, S. Margadonna, K. Prassides, T. J.S. Dennis, H. Shinohara

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

The pressure behavior of the intramolecular phonon modes of the fullerene C₈₄ and its structural stability have been studied for the first time by means of Raman spectroscopy and synchrotron X-ray diffraction at high pressure up to ∼10 GPa. The volume of the cubic unit cell has been measured as a function of pressure. The experimental data fitted by the Mumaghan equation-of-state (EOS) gave K₀ = 19.5 ± 0.9 GPa and K′₀ = 16.4 ± 0.6. The pressure coefficients and Grüneisen parameters of the intramolecular phonon modes of C₈₄ have been determined and compared with those of other fullerenes. The data obtained do not show any phase transition and the pressure behavior of the material is entirely reversible in the pressure region investigated.

Original language	English
Pages (from-to)	63-67
Number of pages	5
Journal	High Pressure Research
Volume	22
Issue number	1
DOIs	https://doi.org/10.1080/08957950211373
Publication status	Published - Apr 2002
Externally published	Yes

Keywords

C
Fullerenes
High-pressure
Raman spectroscopy
X-ray scattering

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@article{680c3f31f8ae4b8984c92f67721e8a0b,

title = "Pressure response of the higher fullerene C84 studied by Raman and X-ray scattering",

abstract = "The pressure behavior of the intramolecular phonon modes of the fullerene C84 and its structural stability have been studied for the first time by means of Raman spectroscopy and synchrotron X-ray diffraction at high pressure up to ∼10 GPa. The volume of the cubic unit cell has been measured as a function of pressure. The experimental data fitted by the Mumaghan equation-of-state (EOS) gave K0 = 19.5 ± 0.9 GPa and K′0 = 16.4 ± 0.6. The pressure coefficients and Gr{\"u}neisen parameters of the intramolecular phonon modes of C84 have been determined and compared with those of other fullerenes. The data obtained do not show any phase transition and the pressure behavior of the material is entirely reversible in the pressure region investigated.",

keywords = "C, Fullerenes, High-pressure, Raman spectroscopy, X-ray scattering",

author = "S. Assimopoulos and Meletov, {K. P.} and Kourouklis, {G. A.} and I. Margiolaki and S. Margadonna and K. Prassides and Dennis, {T. J.S.} and H. Shinohara",

note = "Funding Information: The support by the General Secretariat for Research and Technology (GSRT), Greece, grant # PENED99, 99ED=62 is acknowledged. K. P. M. acknowledges the support by the GSRT, Greece, and the Russian Foundation for Fundamental Research, Russia, grant # 99-02-17555. We thank the ESRF for provision of beamtime, NEDO for support under the Frontier Carbon Technology Program (KP) and JSPS for support under the Future Program for New Carbon Nanomaterials (HS).",

year = "2002",

month = apr,

doi = "10.1080/08957950211373",

language = "English",

volume = "22",

pages = "63--67",

journal = "High Pressure Research",

issn = "0895-7959",

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TY - JOUR

T1 - Pressure response of the higher fullerene C84 studied by Raman and X-ray scattering

AU - Assimopoulos, S.

AU - Meletov, K. P.

AU - Kourouklis, G. A.

AU - Margiolaki, I.

AU - Margadonna, S.

AU - Prassides, K.

AU - Dennis, T. J.S.

AU - Shinohara, H.

N1 - Funding Information: The support by the General Secretariat for Research and Technology (GSRT), Greece, grant # PENED99, 99ED=62 is acknowledged. K. P. M. acknowledges the support by the GSRT, Greece, and the Russian Foundation for Fundamental Research, Russia, grant # 99-02-17555. We thank the ESRF for provision of beamtime, NEDO for support under the Frontier Carbon Technology Program (KP) and JSPS for support under the Future Program for New Carbon Nanomaterials (HS).

PY - 2002/4

Y1 - 2002/4

N2 - The pressure behavior of the intramolecular phonon modes of the fullerene C84 and its structural stability have been studied for the first time by means of Raman spectroscopy and synchrotron X-ray diffraction at high pressure up to ∼10 GPa. The volume of the cubic unit cell has been measured as a function of pressure. The experimental data fitted by the Mumaghan equation-of-state (EOS) gave K0 = 19.5 ± 0.9 GPa and K′0 = 16.4 ± 0.6. The pressure coefficients and Grüneisen parameters of the intramolecular phonon modes of C84 have been determined and compared with those of other fullerenes. The data obtained do not show any phase transition and the pressure behavior of the material is entirely reversible in the pressure region investigated.

AB - The pressure behavior of the intramolecular phonon modes of the fullerene C84 and its structural stability have been studied for the first time by means of Raman spectroscopy and synchrotron X-ray diffraction at high pressure up to ∼10 GPa. The volume of the cubic unit cell has been measured as a function of pressure. The experimental data fitted by the Mumaghan equation-of-state (EOS) gave K0 = 19.5 ± 0.9 GPa and K′0 = 16.4 ± 0.6. The pressure coefficients and Grüneisen parameters of the intramolecular phonon modes of C84 have been determined and compared with those of other fullerenes. The data obtained do not show any phase transition and the pressure behavior of the material is entirely reversible in the pressure region investigated.

KW - C

KW - Fullerenes

KW - High-pressure

KW - Raman spectroscopy

KW - X-ray scattering

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DO - 10.1080/08957950211373

M3 - Article

AN - SCOPUS:0348002033

SN - 0895-7959

VL - 22

SP - 63

EP - 67

JO - High Pressure Research

JF - High Pressure Research

IS - 1

ER -

Pressure response of the higher fullerene C₈₄ studied by Raman and X-ray scattering

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