Novel silver(I)-organic coordination polymers: Conversion of extended structures in the solid state as driven by argentophilic interactions

Long Pan, E. Brice Woodlock, Xiaotai Wang*, Kin Chung Lam, Arnold L. Rheingold

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

154 Citations (Scopus)

Abstract

Structurally distinct coordination polymers [Ag(bpp)]ClO4 1 and [Ag(bpp)]PF6 2 [bpp = 1,3-bis(4-pyridyl)propane] have been assembled; the conversion of 1 into 2 on treatment with NaPF6 is driven by argentophilic interactions and is the first such transformation reported for silver(I)-organic coordination polymers.

Original languageEnglish
Pages (from-to)1762-1763
Number of pages2
JournalChemical Communications
Volume1
Issue number18
DOIs
Publication statusPublished - 2001
Externally publishedYes

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