A new porous three-dimensional lanthanide coordination polymer

Long Pan; E. Brice Woodlock; Xiaotai Wang; Chong Zheng

doi:10.1021/ic000209d

A new porous three-dimensional lanthanide coordination polymer

Long Pan, E. Brice Woodlock, Xiaotai Wang^*, Chong Zheng

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

186 Citations (Scopus)

Abstract

The open-framework coordination polymer [Er(C₉H₉-O₆)(H₂O)₂]·2.5H₂O (C₉H₉O₆ = cis,cis-1,3,5-cyclohexanetricarboxylate) has been synthesized under hydrothermal conditions. Each Er ion is coordinated to nine oxygen atoms belonging to two water molecules and five carboxylate ligands. Its 3-D polymeric structure possesses channels containing the guest water molecules that can be removed to afford a porous material [Er(C₉H₉O₆)(H₂O)₂]. The metalorganic framework in [Er(C₉H₉O₆)(H₂O)₂] can withstand the removal of 1 equiv of coordinated water.

Original language	English
Pages (from-to)	4174-4178
Number of pages	5
Journal	Inorganic Chemistry
Volume	39
Issue number	18
DOIs	https://doi.org/10.1021/ic000209d
Publication status	Published - 4 Sept 2000
Externally published	Yes

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title = "A new porous three-dimensional lanthanide coordination polymer",

abstract = "The open-framework coordination polymer [Er(C9H9-O6)(H2O)2]·2.5H2O (C9H9O6 = cis,cis-1,3,5-cyclohexanetricarboxylate) has been synthesized under hydrothermal conditions. Each Er ion is coordinated to nine oxygen atoms belonging to two water molecules and five carboxylate ligands. Its 3-D polymeric structure possesses channels containing the guest water molecules that can be removed to afford a porous material [Er(C9H9O6)(H2O)2]. The metalorganic framework in [Er(C9H9O6)(H2O)2] can withstand the removal of 1 equiv of coordinated water.",

author = "Long Pan and Woodlock, {E. Brice} and Xiaotai Wang and Chong Zheng",

year = "2000",

month = sep,

day = "4",

doi = "10.1021/ic000209d",

language = "English",

volume = "39",

pages = "4174--4178",

journal = "Inorganic Chemistry",

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T1 - A new porous three-dimensional lanthanide coordination polymer

AU - Pan, Long

AU - Woodlock, E. Brice

AU - Wang, Xiaotai

AU - Zheng, Chong

PY - 2000/9/4

Y1 - 2000/9/4

N2 - The open-framework coordination polymer [Er(C9H9-O6)(H2O)2]·2.5H2O (C9H9O6 = cis,cis-1,3,5-cyclohexanetricarboxylate) has been synthesized under hydrothermal conditions. Each Er ion is coordinated to nine oxygen atoms belonging to two water molecules and five carboxylate ligands. Its 3-D polymeric structure possesses channels containing the guest water molecules that can be removed to afford a porous material [Er(C9H9O6)(H2O)2]. The metalorganic framework in [Er(C9H9O6)(H2O)2] can withstand the removal of 1 equiv of coordinated water.

AB - The open-framework coordination polymer [Er(C9H9-O6)(H2O)2]·2.5H2O (C9H9O6 = cis,cis-1,3,5-cyclohexanetricarboxylate) has been synthesized under hydrothermal conditions. Each Er ion is coordinated to nine oxygen atoms belonging to two water molecules and five carboxylate ligands. Its 3-D polymeric structure possesses channels containing the guest water molecules that can be removed to afford a porous material [Er(C9H9O6)(H2O)2]. The metalorganic framework in [Er(C9H9O6)(H2O)2] can withstand the removal of 1 equiv of coordinated water.

UR - http://www.scopus.com/inward/record.url?scp=0034604944&partnerID=8YFLogxK

U2 - 10.1021/ic000209d

DO - 10.1021/ic000209d

M3 - Article

AN - SCOPUS:0034604944

SN - 0020-1669

VL - 39

SP - 4174

EP - 4178

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 18

ER -

A new porous three-dimensional lanthanide coordination polymer

Abstract

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