TY - JOUR
T1 - A Nano Nickel (II) Metal–Organic Coordination Compound for Nano Nickel (II) Oxide
T2 - Sonochemical Synthesis and Characterization
AU - Hanifehpour, Younes
AU - Mirtamizdoust, Babak
AU - Wang, Ruiyao
AU - Anbarteh, Saeed
AU - Joo, Sang Woo
N1 - Publisher Copyright:
© 2017, Springer Science+Business Media New York.
PY - 2017/7/1
Y1 - 2017/7/1
N2 - A sonochemical method was used to synthesize a nickel (II) coordination complex, [Ni(phen)3](BF4)2·H2O}n (1) (phen = 1,10-phenamthroline), with particle sizes in the range of 40–120 nm. The new nanostructure was characterized by scanning electron microscopy (SEM), X-ray powder diffraction (PXRD), infrared, and elemental analyses. Compound 1 was structurally characterized by single-crystal X-ray diffraction, and the data show that the Ni(II) ions are coordinated by six N-donor atoms from three phen ligands. The charge was balanced by two tetrafluoroborate anions. The supramolecular features in these complexes are guided and controlled by weak directional intermolecular interactions. They are further extended into a three-dimensional (3-D) supramolecular structure by weak π–π directional intermolecular interactions. Cubic NiO nanoparticles with sizes of 5–40 nm were obtained by thermolysis of 1 at 180 °C.
AB - A sonochemical method was used to synthesize a nickel (II) coordination complex, [Ni(phen)3](BF4)2·H2O}n (1) (phen = 1,10-phenamthroline), with particle sizes in the range of 40–120 nm. The new nanostructure was characterized by scanning electron microscopy (SEM), X-ray powder diffraction (PXRD), infrared, and elemental analyses. Compound 1 was structurally characterized by single-crystal X-ray diffraction, and the data show that the Ni(II) ions are coordinated by six N-donor atoms from three phen ligands. The charge was balanced by two tetrafluoroborate anions. The supramolecular features in these complexes are guided and controlled by weak directional intermolecular interactions. They are further extended into a three-dimensional (3-D) supramolecular structure by weak π–π directional intermolecular interactions. Cubic NiO nanoparticles with sizes of 5–40 nm were obtained by thermolysis of 1 at 180 °C.
KW - 1,10-Phenamthroline
KW - Crystal structure
KW - Nano complex
KW - Nano nickel oxide
KW - Ni(II)
KW - Ultrasonic irradiation
UR - http://www.scopus.com/inward/record.url?scp=85018816436&partnerID=8YFLogxK
U2 - 10.1007/s10904-017-0554-4
DO - 10.1007/s10904-017-0554-4
M3 - Article
AN - SCOPUS:85018816436
SN - 1574-1443
VL - 27
SP - 1045
EP - 1052
JO - Journal of Inorganic and Organometallic Polymers and Materials
JF - Journal of Inorganic and Organometallic Polymers and Materials
IS - 4
ER -