Z-scheme g-C3N4 nanosheet/MgBi2O6 systems with the visible light response for impressive photocatalytic organic contaminants degradation

Van Huy Nguyen*, Mitra Mousavi, Jahan B. Ghasemi*, Seyed Ali Delbari, Quyet Van Le, Abbas Sabahi Namini*, Mehdi Shahedi Asl, Mohammadreza Shokouhimehr, Yashar Azizian-Kalandaragh, Mohsen Mohammadi

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

17 Citations (Scopus)

Abstract

In this research paper, we have constructed novel Z-scheme g-C3N4 nanosheet/MgBi2O6 systems with the visible light response for the photocatalytic elimination of cationic pollutants such as MB, RhB, anionic pollutants such as CR, MO, and also colorless pollutant such as phenol. The batch tests illustrated that the first-order kinetic constant of the amount-optimized nanocomposite of gCN-NS/MgBi2O6 with a mass ratio of 70:30 was 1337.84 × 10−4 min−1 in the degradation of RhB, which was 77.3-folds better than that of g-C3N4 alone. Moreover, using various quenchers, the scavenging test outcomes demonstrated that OH, O2, and h+ have a remarkable role in the photocatalytic elimination process. The photostability of gCN-NS/MgBi2O6 system was studied over four consecutive cycles revealing good reusability and stability. Finally, according to the energy band matching theory, the mechanism of Z-scheme charges movement was also offered to boost different pollutants photoactivity. Our current work opens up new avenue for further research.

Original languageEnglish
Article number113023
JournalJournal of Photochemistry and Photobiology A: Chemistry
Volume406
DOIs
Publication statusPublished - 1 Feb 2021
Externally publishedYes

Keywords

  • g-CN/MgBiO
  • Heterostructured nanocomposite
  • Photocatalysis
  • Pollutant photodegradation
  • Z-scheme mechanism

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