Vibrational infrared spectra of the two major isomers of [84]fullerene: C84{D2(IV)} and C84{D2d(II)}

T. J.S. Dennis; M. Hulman; H. Kuzmany; H. Shinohara

doi:10.1021/jp0006835

Vibrational infrared spectra of the two major isomers of [84]fullerene: C₈₄{D₂(IV)} and C₈₄{D_2d(II)}

T. J.S. Dennis^*, M. Hulman, H. Kuzmany, H. Shinohara

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

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Abstract

We present the first vibrational study of isomers of the same fullerene; C₈₄D₂(IV)} and C₈₄(D_2d(II)}. Owing to their lower symmetry, the spectra of these isomers exhibit many more lines than the previously studied fullerenes C₆₀, C₇₀, and C₇₆. The temperature dependence of the IR spectra indicates a structural phase change occurs, for both isomers, near 150 K.

Original language	English
Pages (from-to)	5411-5413
Number of pages	3
Journal	Journal of Physical Chemistry B
Volume	104
Issue number	23
DOIs	https://doi.org/10.1021/jp0006835
Publication status	Published - 15 Jun 2000
Externally published	Yes

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title = "Vibrational infrared spectra of the two major isomers of [84]fullerene: C84{D2(IV)} and C84{D2d(II)}",

abstract = "We present the first vibrational study of isomers of the same fullerene; C84D2(IV)} and C84(D2d(II)}. Owing to their lower symmetry, the spectra of these isomers exhibit many more lines than the previously studied fullerenes C60, C70, and C76. The temperature dependence of the IR spectra indicates a structural phase change occurs, for both isomers, near 150 K.",

author = "Dennis, {T. J.S.} and M. Hulman and H. Kuzmany and H. Shinohara",

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T2 - C84{D2(IV)} and C84{D2d(II)}

AU - Dennis, T. J.S.

AU - Hulman, M.

AU - Kuzmany, H.

AU - Shinohara, H.

PY - 2000/6/15

Y1 - 2000/6/15

N2 - We present the first vibrational study of isomers of the same fullerene; C84D2(IV)} and C84(D2d(II)}. Owing to their lower symmetry, the spectra of these isomers exhibit many more lines than the previously studied fullerenes C60, C70, and C76. The temperature dependence of the IR spectra indicates a structural phase change occurs, for both isomers, near 150 K.

AB - We present the first vibrational study of isomers of the same fullerene; C84D2(IV)} and C84(D2d(II)}. Owing to their lower symmetry, the spectra of these isomers exhibit many more lines than the previously studied fullerenes C60, C70, and C76. The temperature dependence of the IR spectra indicates a structural phase change occurs, for both isomers, near 150 K.

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U2 - 10.1021/jp0006835

DO - 10.1021/jp0006835

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AN - SCOPUS:0033686319

SN - 1520-6106

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JO - Journal of Physical Chemistry B

JF - Journal of Physical Chemistry B

IS - 23

ER -

Vibrational infrared spectra of the two major isomers of [84]fullerene: C₈₄{D₂(IV)} and C₈₄{D_2d(II)}

Abstract

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