Total Syntheses of Brassicicenes A, R, and T

Bolin Chen; Yufen Yang; Xijing Zhang; Dongdong Xu; Yuanjun Sun; Yue Chen; Liang Wang

doi:10.1021/acs.orglett.3c03355

Total Syntheses of Brassicicenes A, R, and T

Bolin Chen, Yufen Yang, Xijing Zhang, Dongdong Xu, Yuanjun Sun^*, Yue Chen^*, Liang Wang^*

^*Corresponding author for this work

AoPHA Faculty

Nankai University

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

Here, we report concise and divergent total syntheses of fusicoccane members brassicicenes A, R, and T. The key feature of the synthesis is the rapid construction of the 5/8/5 tricyclic core via four steps: aldol reaction, Stork–Danheiser transposition, and ring-closing metathesis from known compounds followed by concise oxidation state adjustment.

Original language	English
Journal	Organic Letters
DOIs	https://doi.org/10.1021/acs.orglett.3c03355
Publication status	Published - 2023

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10.1021/acs.orglett.3c03355

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title = "Total Syntheses of Brassicicenes A, R, and T",

abstract = "Here, we report concise and divergent total syntheses of fusicoccane members brassicicenes A, R, and T. The key feature of the synthesis is the rapid construction of the 5/8/5 tricyclic core via four steps: aldol reaction, Stork–Danheiser transposition, and ring-closing metathesis from known compounds followed by concise oxidation state adjustment.",

author = "Bolin Chen and Yufen Yang and Xijing Zhang and Dongdong Xu and Yuanjun Sun and Yue Chen and Liang Wang",

year = "2023",

doi = "10.1021/acs.orglett.3c03355",

language = "English",

journal = "Organic Letters",

issn = "1523-7060",

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TY - JOUR

T1 - Total Syntheses of Brassicicenes A, R, and T

AU - Chen, Bolin

AU - Yang, Yufen

AU - Zhang, Xijing

AU - Xu, Dongdong

AU - Sun, Yuanjun

AU - Chen, Yue

AU - Wang, Liang

PY - 2023

Y1 - 2023

N2 - Here, we report concise and divergent total syntheses of fusicoccane members brassicicenes A, R, and T. The key feature of the synthesis is the rapid construction of the 5/8/5 tricyclic core via four steps: aldol reaction, Stork–Danheiser transposition, and ring-closing metathesis from known compounds followed by concise oxidation state adjustment.

AB - Here, we report concise and divergent total syntheses of fusicoccane members brassicicenes A, R, and T. The key feature of the synthesis is the rapid construction of the 5/8/5 tricyclic core via four steps: aldol reaction, Stork–Danheiser transposition, and ring-closing metathesis from known compounds followed by concise oxidation state adjustment.

U2 - 10.1021/acs.orglett.3c03355

DO - 10.1021/acs.orglett.3c03355

M3 - Article

SN - 1523-7060

JO - Organic Letters

JF - Organic Letters

ER -

Total Syntheses of Brassicicenes A, R, and T

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