TY - JOUR
T1 - Three-component reactions leading to 2D and 3D metal-organic frameworks assembled on dinickel-carboxylate secondary building units
AU - Lan, Anjian
AU - Chen, Lian
AU - Yuan, Daqiang
AU - Huang, Yougui
AU - Hong, Maochun
AU - Wang, Xiaotai
N1 - Funding Information:
The authors gratefully acknowledge support for this work from the donors of The Petroleum Research Fund , administrated by the ACS; Research Corporation ; and the Chinese Academy of Sciences . Lan is thankful for a grant from the National Natural Science Foundation of China ( 21071144 ).
PY - 2011/1/12
Y1 - 2011/1/12
N2 - Three-component reactions involving Ni(II) ions and dicarboxylate and bipyridyl ligands under hydrothermal conditions produce two novel metal-organic coordination polymers formulated empirically as [Ni(PDA)(BPE)] (1) and [Ni 2(PDA)2(BPP)(H2O)]·2.5H2O (2), where PDA = 1,4-phenylenediacetate, BPE = 1,2-bis(4-pyridyl)ethane, and BPP = 1,3-bis(4-pyridyl)propane. Both compounds possess 2D or 3D metal-organic frameworks (MOFs) that are assembled on dinickel-carboxylate secondary building units. Compound 1 has a condensed 3D MOF, whereas 2 contains void between 2D MOFs where guest water molecules reside. Both compounds demonstrate antiferromagnetic coupling between Ni(II) ions.
AB - Three-component reactions involving Ni(II) ions and dicarboxylate and bipyridyl ligands under hydrothermal conditions produce two novel metal-organic coordination polymers formulated empirically as [Ni(PDA)(BPE)] (1) and [Ni 2(PDA)2(BPP)(H2O)]·2.5H2O (2), where PDA = 1,4-phenylenediacetate, BPE = 1,2-bis(4-pyridyl)ethane, and BPP = 1,3-bis(4-pyridyl)propane. Both compounds possess 2D or 3D metal-organic frameworks (MOFs) that are assembled on dinickel-carboxylate secondary building units. Compound 1 has a condensed 3D MOF, whereas 2 contains void between 2D MOFs where guest water molecules reside. Both compounds demonstrate antiferromagnetic coupling between Ni(II) ions.
KW - Coordination polymers
KW - Metal-organic frameworks
KW - Nickel(II) complexes
KW - Secondary building units
KW - Three-component reactions
UR - http://www.scopus.com/inward/record.url?scp=78650839232&partnerID=8YFLogxK
U2 - 10.1016/j.poly.2010.09.026
DO - 10.1016/j.poly.2010.09.026
M3 - Article
AN - SCOPUS:78650839232
SN - 0277-5387
VL - 30
SP - 47
EP - 52
JO - Polyhedron
JF - Polyhedron
IS - 1
ER -