Three-component reactions leading to 2D and 3D metal-organic frameworks assembled on dinickel-carboxylate secondary building units

Anjian Lan, Lian Chen, Daqiang Yuan, Yougui Huang, Maochun Hong, Xiaotai Wang*

*Corresponding author for this work

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Abstract

Three-component reactions involving Ni(II) ions and dicarboxylate and bipyridyl ligands under hydrothermal conditions produce two novel metal-organic coordination polymers formulated empirically as [Ni(PDA)(BPE)] (1) and [Ni 2(PDA)2(BPP)(H2O)]·2.5H2O (2), where PDA = 1,4-phenylenediacetate, BPE = 1,2-bis(4-pyridyl)ethane, and BPP = 1,3-bis(4-pyridyl)propane. Both compounds possess 2D or 3D metal-organic frameworks (MOFs) that are assembled on dinickel-carboxylate secondary building units. Compound 1 has a condensed 3D MOF, whereas 2 contains void between 2D MOFs where guest water molecules reside. Both compounds demonstrate antiferromagnetic coupling between Ni(II) ions.

Original languageEnglish
Pages (from-to)47-52
Number of pages6
JournalPolyhedron
Volume30
Issue number1
DOIs
Publication statusPublished - 12 Jan 2011
Externally publishedYes

Keywords

  • Coordination polymers
  • Metal-organic frameworks
  • Nickel(II) complexes
  • Secondary building units
  • Three-component reactions

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Lan, A., Chen, L., Yuan, D., Huang, Y., Hong, M., & Wang, X. (2011). Three-component reactions leading to 2D and 3D metal-organic frameworks assembled on dinickel-carboxylate secondary building units. Polyhedron, 30(1), 47-52. https://doi.org/10.1016/j.poly.2010.09.026