Zhang, F., Li, B., Ren, Q., Mao, H., Xia, Y., Hu, B., Liu, Z., Wang, Z., Shao, Y., Feng, Z., Tan, S., Sun, Y., Ren, Z., Jing, Q., Liu, B., Luo, H., Ma, J., Mei, Y., Wang, C., & Cao, G.-H. (2020). ThMnPnN (Pn = P, As): Synthesis, Structure, and Chemical Pressure Effects. Inorganic Chemistry, 59(5), 2937-2944. https://doi.org/10.1021/acs.inorgchem.9b03294
Zhang, Fuxiang ; Li, Baizhuo ; Ren, Qingyong et al. / ThMnPnN (Pn = P, As): Synthesis, Structure, and Chemical Pressure Effects. In: Inorganic Chemistry. 2020 ; Vol. 59, No. 5. pp. 2937-2944.
@article{d8c135baa83f4156bc10aa7b1875506f,
title = "ThMnPnN (Pn = P, As): Synthesis, Structure, and Chemical Pressure Effects",
abstract = "Mn-based ZrCuSiAs-type pnictides ThMnPnN (Pn = P, As) containing PbO-type Th2N2 layers were synthesized. The crystal and magnetic structures are determined using X-ray and neutron powder diffraction. While neutron diffraction indicates a C-type antiferromagnetic state at 300 K, the temperature dependence of the magnetic susceptibility shows cusps at 36 and 52 K respectively for ThMnPN and ThMnAsN. The susceptibility cusps are ascribed to a spontaneous antiferromagnetic-to-antiferromagnetic transition for Mn2+ moments, which is observed for the first time in Mn-based ZrCuSiAs-type compounds. In addition, measurements of the resistivity and specific heat suggest an abnormal increase in the density of states at the Fermi energy. The result is discussed in terms of the internal chemical pressure effect.",
author = "Fuxiang Zhang and Baizhuo Li and Qingyong Ren and Huican Mao and Yuanhua Xia and Bingfeng Hu and Zichen Liu and Zhicheng Wang and Yeting Shao and Zhifa Feng and Shugang Tan and Yuping Sun and Zhi Ren and Qiang Jing and Bo Liu and Huiqian Luo and Jie Ma and Yuxue Mei and Cao Wang and Guang-Han Cao",
year = "2020",
doi = "10.1021/acs.inorgchem.9b03294",
language = "English",
volume = "59",
pages = "2937--2944",
journal = "Inorganic Chemistry",
issn = "0020-1669",
number = "5",
}
Zhang, F, Li, B, Ren, Q, Mao, H, Xia, Y, Hu, B, Liu, Z, Wang, Z, Shao, Y, Feng, Z, Tan, S, Sun, Y, Ren, Z, Jing, Q, Liu, B, Luo, H, Ma, J, Mei, Y, Wang, C & Cao, G-H 2020, 'ThMnPnN (Pn = P, As): Synthesis, Structure, and Chemical Pressure Effects', Inorganic Chemistry, vol. 59, no. 5, pp. 2937-2944. https://doi.org/10.1021/acs.inorgchem.9b03294
ThMnPnN (Pn = P, As): Synthesis, Structure, and Chemical Pressure Effects. / Zhang, Fuxiang; Li, Baizhuo; Ren, Qingyong et al.
In:
Inorganic Chemistry, Vol. 59, No. 5, 2020, p. 2937-2944.
Research output: Contribution to journal › Article › peer-review
TY - JOUR
T1 - ThMnPnN (Pn = P, As): Synthesis, Structure, and Chemical Pressure Effects
AU - Zhang, Fuxiang
AU - Li, Baizhuo
AU - Ren, Qingyong
AU - Mao, Huican
AU - Xia, Yuanhua
AU - Hu, Bingfeng
AU - Liu, Zichen
AU - Wang, Zhicheng
AU - Shao, Yeting
AU - Feng, Zhifa
AU - Tan, Shugang
AU - Sun, Yuping
AU - Ren, Zhi
AU - Jing, Qiang
AU - Liu, Bo
AU - Luo, Huiqian
AU - Ma, Jie
AU - Mei, Yuxue
AU - Wang, Cao
AU - Cao, Guang-Han
PY - 2020
Y1 - 2020
N2 - Mn-based ZrCuSiAs-type pnictides ThMnPnN (Pn = P, As) containing PbO-type Th2N2 layers were synthesized. The crystal and magnetic structures are determined using X-ray and neutron powder diffraction. While neutron diffraction indicates a C-type antiferromagnetic state at 300 K, the temperature dependence of the magnetic susceptibility shows cusps at 36 and 52 K respectively for ThMnPN and ThMnAsN. The susceptibility cusps are ascribed to a spontaneous antiferromagnetic-to-antiferromagnetic transition for Mn2+ moments, which is observed for the first time in Mn-based ZrCuSiAs-type compounds. In addition, measurements of the resistivity and specific heat suggest an abnormal increase in the density of states at the Fermi energy. The result is discussed in terms of the internal chemical pressure effect.
AB - Mn-based ZrCuSiAs-type pnictides ThMnPnN (Pn = P, As) containing PbO-type Th2N2 layers were synthesized. The crystal and magnetic structures are determined using X-ray and neutron powder diffraction. While neutron diffraction indicates a C-type antiferromagnetic state at 300 K, the temperature dependence of the magnetic susceptibility shows cusps at 36 and 52 K respectively for ThMnPN and ThMnAsN. The susceptibility cusps are ascribed to a spontaneous antiferromagnetic-to-antiferromagnetic transition for Mn2+ moments, which is observed for the first time in Mn-based ZrCuSiAs-type compounds. In addition, measurements of the resistivity and specific heat suggest an abnormal increase in the density of states at the Fermi energy. The result is discussed in terms of the internal chemical pressure effect.
U2 - 10.1021/acs.inorgchem.9b03294
DO - 10.1021/acs.inorgchem.9b03294
M3 - Article
SN - 0020-1669
VL - 59
SP - 2937
EP - 2944
JO - Inorganic Chemistry
JF - Inorganic Chemistry
IS - 5
ER -
Zhang F, Li B, Ren Q, Mao H, Xia Y, Hu B et al. ThMnPnN (Pn = P, As): Synthesis, Structure, and Chemical Pressure Effects. Inorganic Chemistry. 2020;59(5):2937-2944. doi: 10.1021/acs.inorgchem.9b03294
