Thioarsenic compounds exist in the drinking groundwater

J. H. Liang, Z. Chen

Research output: Chapter in Book or Report/Conference proceedingConference Proceedingpeer-review

Abstract

Arsenic (As) polluted groundwater in Northern China was used as drinking water source and caused severe health problems. Characterization of As speciation is crucial to understand the health risk of As and its biogeochemical behaviors in groundwater. In this study, groundwater samples were collected from 26 wells in Northern China. Arsenic species in the groundwater were measured by high-performance liquid chromatography (HPLC) and inductively coupled plasma mass spectrometry (ICP-MS). Thioarsenate, one of the As species that is seldom reported in drinking groundwater, was detected in two-third of the sampling wells, even in the samples with total As concentration lower than 10 µg·L−1. Furthermore, the occurrence of thioarsenate in groundwater samples was dependent on the pH of groundwater, and thioarsenate was transformed to arsenite below a pH value of 8.2. The study demonstrated thioarsenate was prevalent in the alkaline drinking groundwater and would be a new As exposure pathway for the people and livestock living in the As-rich area.

Original languageEnglish
Title of host publicationEnvironmental Arsenic in a ChangingWorld - 7th International Congress and Exhibition Arsenic in the Environment, 2018
EditorsYong-Guan Zhu, Yong-Guan Zhu, Huaming Guo, Huaming Guo, Prosun Bhattacharya, Prosun Bhattacharya, Jochen Bundschuh, Arslan Ahmad, Arslan Ahmad, Arslan Ahmad, Ravi Naidu, Ravi Naidu
PublisherCRC Press/Balkema
Pages223-224
Number of pages2
ISBN (Print)9781138486096
DOIs
Publication statusPublished - 2018
Event7th International Congress and Exhibition Arsenic in the Environment, 2018 - Beijing, China
Duration: 1 Jul 20186 Jul 2018

Publication series

NameEnvironmental Arsenic in a ChangingWorld - 7th International Congress and Exhibition Arsenic in the Environment, 2018

Conference

Conference7th International Congress and Exhibition Arsenic in the Environment, 2018
Country/TerritoryChina
CityBeijing
Period1/07/186/07/18

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