The effect of SO2 on CO2 capture in zeolitic imidazolate frameworks

Lifeng Ding; A. Ozgur Yazaydin

doi:10.1039/c3cp51003d

The effect of SO₂ on CO₂ capture in zeolitic imidazolate frameworks

Lifeng Ding, A. Ozgur Yazaydin^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

56 Citations (Scopus)

Abstract

The CO₂ capture performance of four zeolitic imidazolate frameworks (ZIFs), ZIF-10, ZIF-71, ZIF-68 and ZIF-69, was investigated in the presence of SO₂ using molecular simulations. Our results show that SO₂ is preferentially adsorbed over CO₂. However, it also shows a cooperative effect on CO₂ adsorption. In ZIF-10 and ZIF-71, the SO₂ presence was found to have almost no effect on CO₂ adsorption. In ZIF-68 and ZIF-69, although the two ZIFs adsorbed large amounts of SO₂, the decrease in CO₂ uptake was relatively small due to the cooperative interaction between the SO₂ and CO₂ molecules.

Original language	English
Pages (from-to)	11856-11861
Number of pages	6
Journal	Physical Chemistry Chemical Physics
Volume	15
Issue number	28
DOIs	https://doi.org/10.1039/c3cp51003d
Publication status	Published - 28 Jul 2013
Externally published	Yes

Access to Document

10.1039/c3cp51003d

Cite this

@article{741c37a877c84fce964c82e9f7d89308,

title = "The effect of SO2 on CO2 capture in zeolitic imidazolate frameworks",

abstract = "The CO2 capture performance of four zeolitic imidazolate frameworks (ZIFs), ZIF-10, ZIF-71, ZIF-68 and ZIF-69, was investigated in the presence of SO2 using molecular simulations. Our results show that SO2 is preferentially adsorbed over CO2. However, it also shows a cooperative effect on CO2 adsorption. In ZIF-10 and ZIF-71, the SO2 presence was found to have almost no effect on CO2 adsorption. In ZIF-68 and ZIF-69, although the two ZIFs adsorbed large amounts of SO2, the decrease in CO2 uptake was relatively small due to the cooperative interaction between the SO2 and CO2 molecules.",

author = "Lifeng Ding and Yazaydin, {A. Ozgur}",

year = "2013",

month = jul,

day = "28",

doi = "10.1039/c3cp51003d",

language = "English",

volume = "15",

pages = "11856--11861",

journal = "Physical Chemistry Chemical Physics",

issn = "1463-9076",

number = "28",

}

TY - JOUR

T1 - The effect of SO2 on CO2 capture in zeolitic imidazolate frameworks

AU - Ding, Lifeng

AU - Yazaydin, A. Ozgur

PY - 2013/7/28

Y1 - 2013/7/28

N2 - The CO2 capture performance of four zeolitic imidazolate frameworks (ZIFs), ZIF-10, ZIF-71, ZIF-68 and ZIF-69, was investigated in the presence of SO2 using molecular simulations. Our results show that SO2 is preferentially adsorbed over CO2. However, it also shows a cooperative effect on CO2 adsorption. In ZIF-10 and ZIF-71, the SO2 presence was found to have almost no effect on CO2 adsorption. In ZIF-68 and ZIF-69, although the two ZIFs adsorbed large amounts of SO2, the decrease in CO2 uptake was relatively small due to the cooperative interaction between the SO2 and CO2 molecules.

AB - The CO2 capture performance of four zeolitic imidazolate frameworks (ZIFs), ZIF-10, ZIF-71, ZIF-68 and ZIF-69, was investigated in the presence of SO2 using molecular simulations. Our results show that SO2 is preferentially adsorbed over CO2. However, it also shows a cooperative effect on CO2 adsorption. In ZIF-10 and ZIF-71, the SO2 presence was found to have almost no effect on CO2 adsorption. In ZIF-68 and ZIF-69, although the two ZIFs adsorbed large amounts of SO2, the decrease in CO2 uptake was relatively small due to the cooperative interaction between the SO2 and CO2 molecules.

UR - http://www.scopus.com/inward/record.url?scp=84879861082&partnerID=8YFLogxK

U2 - 10.1039/c3cp51003d

DO - 10.1039/c3cp51003d

M3 - Article

AN - SCOPUS:84879861082

SN - 1463-9076

VL - 15

SP - 11856

EP - 11861

JO - Physical Chemistry Chemical Physics

JF - Physical Chemistry Chemical Physics

IS - 28

ER -

The effect of SO₂ on CO₂ capture in zeolitic imidazolate frameworks

Abstract

Access to Document

Other files and links

Fingerprint

Cite this