TY - JOUR
T1 - Superconducting ground state and electronic properties of σ-Phase Ta–W–Mo-Re-Os high entropy alloys
AU - Krishnan, Manikandan
AU - Meng, Jiao Jiao
AU - Li, Bai Zhuo
AU - Ma, Yanmei
AU - Wang, Cao
AU - Bhoi, Dilip
AU - Uwatoko, Yoshiya
AU - Jing, Qiang
AU - Liu, Bo
N1 - Publisher Copyright:
© 2025
PY - 2025/7
Y1 - 2025/7
N2 - We report on a new member of superconducting high entropy alloys, Ta7W10+xMo30-xRe33Os20, 0≤x ≤ 12 (σ-phase), which was synthesized and its superconducting properties were investigated. It was found that bulk superconductivity with a maximum Tc of 5.9 K observed at x = 0. The superconducting Tc decreases with the increase of x, which is directly associated with a reduction in electron-phonon interactions. At low temperatures, the specific heat demonstrates the presence of conventional, fully gapped superconductivity with weak coupling. The collective pinning of vortices is more dominant because point defects play a significant role, as observed from the thermally activated flux flow behaviour. The electronic parameters in these compounds fall within a conventional range on the Uemura plot, suggesting that σ-phase high entropy alloys have a conventional superconducting ground state.
AB - We report on a new member of superconducting high entropy alloys, Ta7W10+xMo30-xRe33Os20, 0≤x ≤ 12 (σ-phase), which was synthesized and its superconducting properties were investigated. It was found that bulk superconductivity with a maximum Tc of 5.9 K observed at x = 0. The superconducting Tc decreases with the increase of x, which is directly associated with a reduction in electron-phonon interactions. At low temperatures, the specific heat demonstrates the presence of conventional, fully gapped superconductivity with weak coupling. The collective pinning of vortices is more dominant because point defects play a significant role, as observed from the thermally activated flux flow behaviour. The electronic parameters in these compounds fall within a conventional range on the Uemura plot, suggesting that σ-phase high entropy alloys have a conventional superconducting ground state.
KW - High entropy alloys
KW - Superconductivity
KW - Thermal activation flux flow
KW - Uemura plot
KW - Valence electron concentration
KW - σ-phase structure
UR - http://www.scopus.com/inward/record.url?scp=86000171837&partnerID=8YFLogxK
U2 - 10.1016/j.jpcs.2025.112630
DO - 10.1016/j.jpcs.2025.112630
M3 - Article
AN - SCOPUS:86000171837
SN - 0022-3697
VL - 202
JO - Journal of Physics and Chemistry of Solids
JF - Journal of Physics and Chemistry of Solids
M1 - 112630
ER -