Superconducting ground state and electronic properties of σ-Phase Ta–W–Mo-Re-Os high entropy alloys

Manikandan Krishnan, Jiao Jiao Meng, Bai Zhuo Li, Yanmei Ma, Cao Wang, Dilip Bhoi, Yoshiya Uwatoko, Qiang Jing*, Bo Liu*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

We report on a new member of superconducting high entropy alloys, Ta7W10+xMo30-xRe33Os20, 0≤x ≤ 12 (σ-phase), which was synthesized and its superconducting properties were investigated. It was found that bulk superconductivity with a maximum Tc of 5.9 K observed at x = 0. The superconducting Tc decreases with the increase of x, which is directly associated with a reduction in electron-phonon interactions. At low temperatures, the specific heat demonstrates the presence of conventional, fully gapped superconductivity with weak coupling. The collective pinning of vortices is more dominant because point defects play a significant role, as observed from the thermally activated flux flow behaviour. The electronic parameters in these compounds fall within a conventional range on the Uemura plot, suggesting that σ-phase high entropy alloys have a conventional superconducting ground state.

Original languageEnglish
Article number112630
JournalJournal of Physics and Chemistry of Solids
Volume202
DOIs
Publication statusPublished - Jul 2025

Keywords

  • High entropy alloys
  • Superconductivity
  • Thermal activation flux flow
  • Uemura plot
  • Valence electron concentration
  • σ-phase structure

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