Ru-catalyzed 1,4-addition of arylboronic acids to acrylic acid derivatives in the presence of phenols

Lei Zhang; Xiaomin Xie; Zhiyong Peng; Lei Fu; Zhaoguo Zhang

doi:10.1039/c3cc43095b

Ru-catalyzed 1,4-addition of arylboronic acids to acrylic acid derivatives in the presence of phenols

Lei Zhang, Xiaomin Xie, Zhiyong Peng, Lei Fu, Zhaoguo Zhang^*

^*Corresponding author for this work

Shanghai Jiao Tong University

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

[Ru(p-cymene)Cl₂]₂-catalyzed 1,4-addition reactions between arylboronic acids and butyl acrylate and acrylamide in the presence of phenols were investigated, good to excellent yields were obtained. The addition of phenols remarkably promoted the protonolysis and inhibited the β-H elimination of the 1,4-addition intermediates, and also efficiently suppressed the protonolysis of arylboronic acids.

Original language	English
Pages (from-to)	8797-8799
Number of pages	3
Journal	Chemical Communications
Volume	49
Issue number	78
DOIs	https://doi.org/10.1039/c3cc43095b
Publication status	Published - 5 Sept 2013
Externally published	Yes

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title = "Ru-catalyzed 1,4-addition of arylboronic acids to acrylic acid derivatives in the presence of phenols",

abstract = "[Ru(p-cymene)Cl2]2-catalyzed 1,4-addition reactions between arylboronic acids and butyl acrylate and acrylamide in the presence of phenols were investigated, good to excellent yields were obtained. The addition of phenols remarkably promoted the protonolysis and inhibited the β-H elimination of the 1,4-addition intermediates, and also efficiently suppressed the protonolysis of arylboronic acids.",

author = "Lei Zhang and Xiaomin Xie and Zhiyong Peng and Lei Fu and Zhaoguo Zhang",

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T1 - Ru-catalyzed 1,4-addition of arylboronic acids to acrylic acid derivatives in the presence of phenols

AU - Zhang, Lei

AU - Xie, Xiaomin

AU - Peng, Zhiyong

AU - Fu, Lei

AU - Zhang, Zhaoguo

PY - 2013/9/5

Y1 - 2013/9/5

N2 - [Ru(p-cymene)Cl2]2-catalyzed 1,4-addition reactions between arylboronic acids and butyl acrylate and acrylamide in the presence of phenols were investigated, good to excellent yields were obtained. The addition of phenols remarkably promoted the protonolysis and inhibited the β-H elimination of the 1,4-addition intermediates, and also efficiently suppressed the protonolysis of arylboronic acids.

AB - [Ru(p-cymene)Cl2]2-catalyzed 1,4-addition reactions between arylboronic acids and butyl acrylate and acrylamide in the presence of phenols were investigated, good to excellent yields were obtained. The addition of phenols remarkably promoted the protonolysis and inhibited the β-H elimination of the 1,4-addition intermediates, and also efficiently suppressed the protonolysis of arylboronic acids.

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U2 - 10.1039/c3cc43095b

DO - 10.1039/c3cc43095b

M3 - Article

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AN - SCOPUS:84883670809

SN - 1359-7345

VL - 49

SP - 8797

EP - 8799

JO - Chemical Communications

JF - Chemical Communications

IS - 78

ER -

Ru-catalyzed 1,4-addition of arylboronic acids to acrylic acid derivatives in the presence of phenols

Abstract

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