New 1,4,7-triazacyclononane-based functional analogues of the Fe/Cu active site of cytochrome c oxidase: Structure, spectroscopy and electrocatalytic reduction of oxygen

James P. Collman; Reinhold Schwenninger; Miroslav Rapta; Martin Bröring; Lei Fu

doi:10.1039/a807598k

New 1,4,7-triazacyclononane-based functional analogues of the Fe/Cu active site of cytochrome c oxidase: Structure, spectroscopy and electrocatalytic reduction of oxygen

James P. Collman^*, Reinhold Schwenninger, Miroslav Rapta, Martin Bröring, Lei Fu

^*Corresponding author for this work

Stanford University

Research output: Contribution to journal › Article › peer-review

39 Citations (Scopus)

Abstract

Two new covalently linked functional model compounds for the Fe(a3)/Cu(B) active sites of heme-copper oxidases have been prepared and characterized by novel synthetic methodologies; the X-ray structure of the Zn form and the electrocatalytic reduction of O₂ by the Fe/Cu forms are reported.

Original language	English
Pages (from-to)	137-138
Number of pages	2
Journal	Chemical Communications
Issue number	2
DOIs	https://doi.org/10.1039/a807598k
Publication status	Published - 21 Jan 1999
Externally published	Yes

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title = "New 1,4,7-triazacyclononane-based functional analogues of the Fe/Cu active site of cytochrome c oxidase: Structure, spectroscopy and electrocatalytic reduction of oxygen",

abstract = "Two new covalently linked functional model compounds for the Fe(a3)/Cu(B) active sites of heme-copper oxidases have been prepared and characterized by novel synthetic methodologies; the X-ray structure of the Zn form and the electrocatalytic reduction of O2 by the Fe/Cu forms are reported.",

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T2 - Structure, spectroscopy and electrocatalytic reduction of oxygen

AU - Collman, James P.

AU - Schwenninger, Reinhold

AU - Rapta, Miroslav

AU - Bröring, Martin

AU - Fu, Lei

PY - 1999/1/21

Y1 - 1999/1/21

N2 - Two new covalently linked functional model compounds for the Fe(a3)/Cu(B) active sites of heme-copper oxidases have been prepared and characterized by novel synthetic methodologies; the X-ray structure of the Zn form and the electrocatalytic reduction of O2 by the Fe/Cu forms are reported.

AB - Two new covalently linked functional model compounds for the Fe(a3)/Cu(B) active sites of heme-copper oxidases have been prepared and characterized by novel synthetic methodologies; the X-ray structure of the Zn form and the electrocatalytic reduction of O2 by the Fe/Cu forms are reported.

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U2 - 10.1039/a807598k

DO - 10.1039/a807598k

M3 - Article

AN - SCOPUS:0033590474

SN - 1359-7345

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JO - Chemical Communications

JF - Chemical Communications

IS - 2

ER -

New 1,4,7-triazacyclononane-based functional analogues of the Fe/Cu active site of cytochrome c oxidase: Structure, spectroscopy and electrocatalytic reduction of oxygen

Abstract

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