TY - JOUR
T1 - Fractographical characterization of hot pressed and pressureless sintered SiAlON-doped ZrB2-SiC composites
AU - Shahedi Asl, Mehdi
AU - Nayebi, Behzad
AU - Ahmadi, Zohre
AU - Pirmohammadi, Parinaz
AU - Ghassemi Kakroudi, Mahdi
N1 - Publisher Copyright:
© 2015 Elsevier Inc. All rights reserved.
PY - 2015/4
Y1 - 2015/4
N2 - ZrB2-SiC composites doped with 0, 1, 3 and 5 wt.% SiAlON were prepared by hot pressing (under a low pressure of 10 MPa) and pressureless sintering processes at 1900 °C for 2 h. A fractographical approach was employed to investigate the effects of SiAlON addition on the densification behavior in such ceramic composites. Several reported chemical reactions were investigated to indicate the probable mechanisms in the progression of the sintering process and also the potential unfavorable effects of SiAlON in ZrB2-SiC composites. On one hand, results show that the SiAlON addition promotes the densification in the hot pressed samples by the liquid phase formation, as a fully dense composite can be obtained by hot pressing of 5 wt.% SiAlON doped ZrB2-SiC composite. On the other hand, in the pressureless sintering process, more SiAlON content intensifies the formation of gasses which leads to more porosity. In both processes, investigation of fracture surfaces demonstrates the presence of thin layers of glassy phases which act as the sintering aid. The steps of densification process in both hot pressing and pressureless sintering processes were presented by a graphical model.
AB - ZrB2-SiC composites doped with 0, 1, 3 and 5 wt.% SiAlON were prepared by hot pressing (under a low pressure of 10 MPa) and pressureless sintering processes at 1900 °C for 2 h. A fractographical approach was employed to investigate the effects of SiAlON addition on the densification behavior in such ceramic composites. Several reported chemical reactions were investigated to indicate the probable mechanisms in the progression of the sintering process and also the potential unfavorable effects of SiAlON in ZrB2-SiC composites. On one hand, results show that the SiAlON addition promotes the densification in the hot pressed samples by the liquid phase formation, as a fully dense composite can be obtained by hot pressing of 5 wt.% SiAlON doped ZrB2-SiC composite. On the other hand, in the pressureless sintering process, more SiAlON content intensifies the formation of gasses which leads to more porosity. In both processes, investigation of fracture surfaces demonstrates the presence of thin layers of glassy phases which act as the sintering aid. The steps of densification process in both hot pressing and pressureless sintering processes were presented by a graphical model.
KW - Densification
KW - Liquid phase sintering
KW - Microstructure
KW - SiAlON
KW - Silicon carbide
KW - Zirconium diboride
UR - http://www.scopus.com/inward/record.url?scp=84924114508&partnerID=8YFLogxK
U2 - 10.1016/j.matchar.2015.03.002
DO - 10.1016/j.matchar.2015.03.002
M3 - Article
AN - SCOPUS:84924114508
SN - 1044-5803
VL - 102
SP - 137
EP - 145
JO - Materials Characterization
JF - Materials Characterization
ER -