TY - JOUR
T1 - Enhanced saturation magnetization in buckypaper-films of thin walled carbon nanostructures filled with Fe3C, FeCo, FeNi, CoNi, Co and Ni crystals
T2 - the key role of Cl
AU - Guo, Jian
AU - Lan, Mu
AU - Wang, Shanling
AU - He, Yi
AU - Zhang, Sijie
AU - Xiang, Gang
AU - Boi, Filippo S.
N1 - Publisher Copyright:
© the Owner Societies 2015.
PY - 2015/7/21
Y1 - 2015/7/21
N2 - We report an advanced chemical vapour deposition approach which allows the direct in situ synthesis of cm-length ultrathin buckypapers comprising carbon nanostructures filled with Fe3C, FeCo, FeNi, CoNi, Co and Ni by sublimation and pyrolysis of single or combined metallocenes with very low quantities of dichlorobenzene. As a result, extremely high saturation magnetizations of 117 emu g-1, 90 emu g-1 and 80 emu g-1 are obtained for the specific cases of Fe3C, FeCo and FeNi, respectively, while variable saturation magnetizations of 70 emu g-1, 58 emu g-1 and 6.7 emu g-1 are obtained for Co, CoNi and Ni respectively.
AB - We report an advanced chemical vapour deposition approach which allows the direct in situ synthesis of cm-length ultrathin buckypapers comprising carbon nanostructures filled with Fe3C, FeCo, FeNi, CoNi, Co and Ni by sublimation and pyrolysis of single or combined metallocenes with very low quantities of dichlorobenzene. As a result, extremely high saturation magnetizations of 117 emu g-1, 90 emu g-1 and 80 emu g-1 are obtained for the specific cases of Fe3C, FeCo and FeNi, respectively, while variable saturation magnetizations of 70 emu g-1, 58 emu g-1 and 6.7 emu g-1 are obtained for Co, CoNi and Ni respectively.
UR - http://www.scopus.com/inward/record.url?scp=84935446509&partnerID=8YFLogxK
U2 - 10.1039/c5cp02425k
DO - 10.1039/c5cp02425k
M3 - Article
AN - SCOPUS:84935446509
SN - 1463-9076
VL - 17
SP - 18159
EP - 18166
JO - Physical Chemistry Chemical Physics
JF - Physical Chemistry Chemical Physics
IS - 27
ER -