Double single-crystal-to-single-crystal transformation and small-molecule activation in rhodium NHC complexes

Olena V. Zenkina; Eric C. Keske; Ruiyao Wang; Cathleen M. Crudden

doi:10.1002/anie.201103316

Double single-crystal-to-single-crystal transformation and small-molecule activation in rhodium NHC complexes

Olena V. Zenkina, Eric C. Keske, Ruiyao Wang, Cathleen M. Crudden^*

^*Corresponding author for this work

Queen's University Kingston

Research output: Contribution to journal › Article › peer-review

78 Citations (Scopus)

Abstract

Three gases, one crystal: Rhodium NHC complexes undergo back-to-back single-crystal-to-single-crystal transformations by selective nonreversible ligand exchange reactions (see picture). Slow diffusion of O₂ converts a dinitrogen complex into a dioxygen complex, and CO subsequently replaces O₂.

Original language	English
Pages (from-to)	8100-8104
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	50
Issue number	35
DOIs	https://doi.org/10.1002/anie.201103316
Publication status	Published - 22 Aug 2011
Externally published	Yes

Keywords

N-heterocyclic carbenes
X-ray diffraction
hydrides
rhodium
single-crystal reactions

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10.1002/anie.201103316

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abstract = "Three gases, one crystal: Rhodium NHC complexes undergo back-to-back single-crystal-to-single-crystal transformations by selective nonreversible ligand exchange reactions (see picture). Slow diffusion of O2 converts a dinitrogen complex into a dioxygen complex, and CO subsequently replaces O2.",

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AU - Crudden, Cathleen M.

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KW - N-heterocyclic carbenes

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KW - hydrides

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KW - single-crystal reactions

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Double single-crystal-to-single-crystal transformation and small-molecule activation in rhodium NHC complexes

Abstract

Keywords

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