A novel pentadecanuclear neodymium cluster: Synthesis and structure of [Nd15(μ4-tyr)10(μ3-OH) 20(μ2-OH)4(OH)10(μ 2-H2O)(H2O)10][Na(ClO 4)2] ·61H2O

Rui Yao Wang; Zhe Ming Wang; Song Gao; Tian Zhu Jin; Zhi Da Chen; Chun Hua Yan; Guang Xian Xu; Cun Heng He

A novel pentadecanuclear neodymium cluster: Synthesis and structure of [Nd₁₅(μ₄-tyr)₁₀(μ₃-OH) ₂₀(μ₂-OH)₄(OH)₁₀(μ ₂-H₂O)(H₂O)₁₀][Na(ClO ₄)₂] ·61H₂O

Rui Yao Wang^*, Zhe Ming Wang, Song Gao, Tian Zhu Jin, Zhi Da Chen, Chun Hua Yan, Guang Xian Xu, Cun Heng He

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

The title complex was synthesized by dissolving tyrosine (tyr) in an aqueous solution of Nd(ClO₄)₃ at NpH5, and its crystal structure was determined by X-ray diffraction methods. The complex is a novel pentadecanuclear with the 15 Nd³⁺ ions connected by μ₃-OH^- ions. The tyrosine ligands are all in their anionic form, and each coordinates to the neodymium ions via the nitrogen atom of the amino group and the two carboxyl oxygen atoms. The molecule a barrel structure.

Original language	English
Pages (from-to)	1141-1144
Number of pages	4
Journal	Chinese Chemical Letters
Volume	9
Issue number	12
Publication status	Published - 1998
Externally published	Yes

Keywords

Neodymium
Pentadecanuclear cluster
Tyrosine

Cite this

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title = "A novel pentadecanuclear neodymium cluster: Synthesis and structure of [Nd15(μ4-tyr)10(μ3-OH) 20(μ2-OH)4(OH)10(μ 2-H2O)(H2O)10][Na(ClO 4)2] ·61H2O",

abstract = "The title complex was synthesized by dissolving tyrosine (tyr) in an aqueous solution of Nd(ClO4)3 at NpH5, and its crystal structure was determined by X-ray diffraction methods. The complex is a novel pentadecanuclear with the 15 Nd3+ ions connected by μ3-OH- ions. The tyrosine ligands are all in their anionic form, and each coordinates to the neodymium ions via the nitrogen atom of the amino group and the two carboxyl oxygen atoms. The molecule a barrel structure.",

keywords = "Neodymium, Pentadecanuclear cluster, Tyrosine",

author = "Wang, {Rui Yao} and Wang, {Zhe Ming} and Song Gao and Jin, {Tian Zhu} and Chen, {Zhi Da} and Yan, {Chun Hua} and Xu, {Guang Xian} and He, {Cun Heng}",

year = "1998",

language = "English",

volume = "9",

pages = "1141--1144",

journal = "Chinese Chemical Letters",

issn = "1001-8417",

number = "12",

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TY - JOUR

T1 - A novel pentadecanuclear neodymium cluster

T2 - Synthesis and structure of [Nd15(μ4-tyr)10(μ3-OH) 20(μ2-OH)4(OH)10(μ 2-H2O)(H2O)10][Na(ClO 4)2] ·61H2O

AU - Wang, Rui Yao

AU - Wang, Zhe Ming

AU - Gao, Song

AU - Jin, Tian Zhu

AU - Chen, Zhi Da

AU - Yan, Chun Hua

AU - Xu, Guang Xian

AU - He, Cun Heng

PY - 1998

Y1 - 1998

N2 - The title complex was synthesized by dissolving tyrosine (tyr) in an aqueous solution of Nd(ClO4)3 at NpH5, and its crystal structure was determined by X-ray diffraction methods. The complex is a novel pentadecanuclear with the 15 Nd3+ ions connected by μ3-OH- ions. The tyrosine ligands are all in their anionic form, and each coordinates to the neodymium ions via the nitrogen atom of the amino group and the two carboxyl oxygen atoms. The molecule a barrel structure.

AB - The title complex was synthesized by dissolving tyrosine (tyr) in an aqueous solution of Nd(ClO4)3 at NpH5, and its crystal structure was determined by X-ray diffraction methods. The complex is a novel pentadecanuclear with the 15 Nd3+ ions connected by μ3-OH- ions. The tyrosine ligands are all in their anionic form, and each coordinates to the neodymium ions via the nitrogen atom of the amino group and the two carboxyl oxygen atoms. The molecule a barrel structure.

KW - Neodymium

KW - Pentadecanuclear cluster

KW - Tyrosine

UR - http://www.scopus.com/inward/record.url?scp=0007404956&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0007404956

SN - 1001-8417

VL - 9

SP - 1141

EP - 1144

JO - Chinese Chemical Letters

JF - Chinese Chemical Letters

IS - 12

ER -

A novel pentadecanuclear neodymium cluster: Synthesis and structure of [Nd15(μ4-tyr)10(μ3-OH) 20(μ2-OH)4(OH)10(μ 2-H2O)(H2O)10][Na(ClO 4)2] ·61H2O

Abstract

Keywords

Other files and links

Cite this

A novel pentadecanuclear neodymium cluster: Synthesis and structure of [Nd₁₅(μ₄-tyr)₁₀(μ₃-OH) ₂₀(μ₂-OH)₄(OH)₁₀(μ ₂-H₂O)(H₂O)₁₀][Na(ClO ₄)₂] ·61H₂O