3D Lanthanide-organic coordination polymers built upon infinite 1D secondary building units

Xiaotai Wang; Haif Alshammary; Rongrong Zhang; Arezou Seifpour; Joe T. Villalva; Zili Xu; Chong Zheng; Jian Rong Li; Xiao Ying Huang

doi:10.1016/j.poly.2008.08.012

3D Lanthanide-organic coordination polymers built upon infinite 1D secondary building units

Xiaotai Wang^*, Haif Alshammary, Rongrong Zhang, Arezou Seifpour, Joe T. Villalva, Zili Xu, Chong Zheng, Jian Rong Li, Xiao Ying Huang

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

Hydrothermal reactions of Ln(NO₃)₃ (Ln = La, Eu) with 1,4-phenylenedipropionic acid (H₂PDP) generate 3D coordination polymers with the empirical formula [Ln₂(PDP)₃(H₂O)₂]. The isostructural compounds crystallize in triclinic space group P over(1, ̄). Each Ln(III) ion is nine-coordinate through ligation to one water molecule and eight carboxylate oxygen atoms. The 3D network structure of [Ln₂(PDP)₃(H₂O)₂] consists of infinite 1D Ln(H₂O)-OOC secondary building units (SBUs) that are cross-linked via -CH₂CH₂C₆H₄CH₂CH₂- tethers of the PDP anions.

Original language	English
Pages (from-to)	3439-3442
Number of pages	4
Journal	Polyhedron
Volume	27
Issue number	17
DOIs	https://doi.org/10.1016/j.poly.2008.08.012
Publication status	Published - 25 Nov 2008
Externally published	Yes

Keywords

Lanthanide complexes
Lanthanide-carboxylate coordination polymers
Metal-organic frameworks

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10.1016/j.poly.2008.08.012

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@article{4d4940dc39cf4694b9b42cea31b702fe,

title = "3D Lanthanide-organic coordination polymers built upon infinite 1D secondary building units",

abstract = "Hydrothermal reactions of Ln(NO3)3 (Ln = La, Eu) with 1,4-phenylenedipropionic acid (H2PDP) generate 3D coordination polymers with the empirical formula [Ln2(PDP)3(H2O)2]. The isostructural compounds crystallize in triclinic space group P over(1,{\= }). Each Ln(III) ion is nine-coordinate through ligation to one water molecule and eight carboxylate oxygen atoms. The 3D network structure of [Ln2(PDP)3(H2O)2] consists of infinite 1D Ln(H2O)-OOC secondary building units (SBUs) that are cross-linked via -CH2CH2C6H4CH2CH2- tethers of the PDP anions.",

keywords = "Lanthanide complexes, Lanthanide-carboxylate coordination polymers, Metal-organic frameworks",

author = "Xiaotai Wang and Haif Alshammary and Rongrong Zhang and Arezou Seifpour and Villalva, {Joe T.} and Zili Xu and Chong Zheng and Li, {Jian Rong} and Huang, {Xiao Ying}",

note = "Funding Information: The authors gratefully acknowledge support for this work from the donors of The Petroleum Research Fund, administrated by the ACS; the National Science Foundation (Grant DMR-0094872); Research Corporation; and Beijing Institute of Petrochemical Technology.",

year = "2008",

month = nov,

day = "25",

doi = "10.1016/j.poly.2008.08.012",

language = "English",

volume = "27",

pages = "3439--3442",

journal = "Polyhedron",

issn = "0277-5387",

number = "17",

}

TY - JOUR

T1 - 3D Lanthanide-organic coordination polymers built upon infinite 1D secondary building units

AU - Wang, Xiaotai

AU - Alshammary, Haif

AU - Zhang, Rongrong

AU - Seifpour, Arezou

AU - Villalva, Joe T.

AU - Xu, Zili

AU - Zheng, Chong

AU - Li, Jian Rong

AU - Huang, Xiao Ying

N1 - Funding Information: The authors gratefully acknowledge support for this work from the donors of The Petroleum Research Fund, administrated by the ACS; the National Science Foundation (Grant DMR-0094872); Research Corporation; and Beijing Institute of Petrochemical Technology.

PY - 2008/11/25

Y1 - 2008/11/25

N2 - Hydrothermal reactions of Ln(NO3)3 (Ln = La, Eu) with 1,4-phenylenedipropionic acid (H2PDP) generate 3D coordination polymers with the empirical formula [Ln2(PDP)3(H2O)2]. The isostructural compounds crystallize in triclinic space group P over(1, ̄). Each Ln(III) ion is nine-coordinate through ligation to one water molecule and eight carboxylate oxygen atoms. The 3D network structure of [Ln2(PDP)3(H2O)2] consists of infinite 1D Ln(H2O)-OOC secondary building units (SBUs) that are cross-linked via -CH2CH2C6H4CH2CH2- tethers of the PDP anions.

AB - Hydrothermal reactions of Ln(NO3)3 (Ln = La, Eu) with 1,4-phenylenedipropionic acid (H2PDP) generate 3D coordination polymers with the empirical formula [Ln2(PDP)3(H2O)2]. The isostructural compounds crystallize in triclinic space group P over(1, ̄). Each Ln(III) ion is nine-coordinate through ligation to one water molecule and eight carboxylate oxygen atoms. The 3D network structure of [Ln2(PDP)3(H2O)2] consists of infinite 1D Ln(H2O)-OOC secondary building units (SBUs) that are cross-linked via -CH2CH2C6H4CH2CH2- tethers of the PDP anions.

KW - Lanthanide complexes

KW - Lanthanide-carboxylate coordination polymers

KW - Metal-organic frameworks

UR - http://www.scopus.com/inward/record.url?scp=55549141818&partnerID=8YFLogxK

U2 - 10.1016/j.poly.2008.08.012

DO - 10.1016/j.poly.2008.08.012

M3 - Article

AN - SCOPUS:55549141818

SN - 0277-5387

VL - 27

SP - 3439

EP - 3442

JO - Polyhedron

JF - Polyhedron

IS - 17

ER -

3D Lanthanide-organic coordination polymers built upon infinite 1D secondary building units

Abstract

Keywords

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