Total Syntheses of Brassicicenes A, R, and T

Bolin Chen, Yufen Yang, Xijing Zhang, Dongdong Xu, Yuanjun Sun*, Yue Chen*, Liang Wang*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

2 Citations (Scopus)

Abstract

Here, we report concise and divergent total syntheses of fusicoccane members brassicicenes A, R, and T. The key feature of the synthesis is the rapid construction of the 5/8/5 tricyclic core via four steps: aldol reaction, Stork–Danheiser transposition, and ring-closing metathesis from known compounds followed by concise oxidation state adjustment.
Original languageEnglish
JournalOrganic Letters
DOIs
Publication statusPublished - 2023

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