The magnetic circular dichroism and absorption spectra of C60 isolated in Ar matrices

Z. Gasyna; P. N. Schatz; J. P. Hare; T. J. Dennis; H. W. Kroto; R. Taylor; D. R.M. Walton

doi:10.1016/0009-2614(91)80064-5

The magnetic circular dichroism and absorption spectra of C₆₀ isolated in Ar matrices

Z. Gasyna^*, P. N. Schatz, J. P. Hare, T. J. Dennis, H. W. Kroto, R. Taylor, D. R.M. Walton

^*Corresponding author for this work

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Abstract

The absorption and magnetic circular dichroism (MCD) spectra of C₆₀ isolated in Ar matrices have been measured in the visible and near-ultraviolet. The first two allowed bands (at ≈ 326 and ≈253 nm) show substantial negative A terms. Sharp, weak vibronic structure showing clear evidence of Jahn-Teller activity is observed in both the 400 and 600 nm regions. Detailed assignments are proposed for the resolved spectral features.

Original language	English
Pages (from-to)	283-291
Number of pages	9
Journal	Chemical Physics Letters
Volume	183
Issue number	3-4
DOIs	https://doi.org/10.1016/0009-2614(91)80064-5
Publication status	Published - 30 Aug 1991
Externally published	Yes

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title = "The magnetic circular dichroism and absorption spectra of C60 isolated in Ar matrices",

abstract = "The absorption and magnetic circular dichroism (MCD) spectra of C60 isolated in Ar matrices have been measured in the visible and near-ultraviolet. The first two allowed bands (at ≈ 326 and ≈253 nm) show substantial negative A terms. Sharp, weak vibronic structure showing clear evidence of Jahn-Teller activity is observed in both the 400 and 600 nm regions. Detailed assignments are proposed for the resolved spectral features.",

author = "Z. Gasyna and Schatz, {P. N.} and Hare, {J. P.} and Dennis, {T. J.} and Kroto, {H. W.} and R. Taylor and Walton, {D. R.M.}",

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AU - Gasyna, Z.

AU - Schatz, P. N.

AU - Hare, J. P.

AU - Dennis, T. J.

AU - Kroto, H. W.

AU - Taylor, R.

AU - Walton, D. R.M.

PY - 1991/8/30

Y1 - 1991/8/30

N2 - The absorption and magnetic circular dichroism (MCD) spectra of C60 isolated in Ar matrices have been measured in the visible and near-ultraviolet. The first two allowed bands (at ≈ 326 and ≈253 nm) show substantial negative A terms. Sharp, weak vibronic structure showing clear evidence of Jahn-Teller activity is observed in both the 400 and 600 nm regions. Detailed assignments are proposed for the resolved spectral features.

AB - The absorption and magnetic circular dichroism (MCD) spectra of C60 isolated in Ar matrices have been measured in the visible and near-ultraviolet. The first two allowed bands (at ≈ 326 and ≈253 nm) show substantial negative A terms. Sharp, weak vibronic structure showing clear evidence of Jahn-Teller activity is observed in both the 400 and 600 nm regions. Detailed assignments are proposed for the resolved spectral features.

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U2 - 10.1016/0009-2614(91)80064-5

DO - 10.1016/0009-2614(91)80064-5

M3 - Article

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VL - 183

SP - 283

EP - 291

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 3-4

ER -

The magnetic circular dichroism and absorption spectra of C₆₀ isolated in Ar matrices

Abstract

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