TY - JOUR
T1 - The anionic coordination polymer {K2[PtII 2AgI8(2,2′-bipyridine)2(O 2CCF3)14]}n
AU - Hudson, Zachary M.
AU - Sun, Yi
AU - Ross, Bryan
AU - Wang, Rui Yao
AU - Wang, Suning
PY - 2009
Y1 - 2009
N2 - The trimetallic compound catena-poly[dipotassium(I) [bis-(2,2′- bipyridine)di-μ3-trifluoro-acetato-dodeca-2-trifluoro-acetato- diplatinum(II)octa-silver(I)]], K2 [Pt2Ag8 (C2F3O2)14(C10H 8N2)2], forms an extended structure in the solid state. Electrostatic inter-actions involving the K+ ions play a key role in the formation of the extended structure in three dimensions. The AgI ions form one-dimensional coordination polymers, with alternating Ag2 and Ag6 units linked by CF3CO2 - ligands. Pt⋯Pt inter-actions perpendicular to the one-dimensional polymerization axis provide another element of long-range order, and electrostatic inter-actions with K+ ions provide connectivity between adjacent polymeric structures.
AB - The trimetallic compound catena-poly[dipotassium(I) [bis-(2,2′- bipyridine)di-μ3-trifluoro-acetato-dodeca-2-trifluoro-acetato- diplatinum(II)octa-silver(I)]], K2 [Pt2Ag8 (C2F3O2)14(C10H 8N2)2], forms an extended structure in the solid state. Electrostatic inter-actions involving the K+ ions play a key role in the formation of the extended structure in three dimensions. The AgI ions form one-dimensional coordination polymers, with alternating Ag2 and Ag6 units linked by CF3CO2 - ligands. Pt⋯Pt inter-actions perpendicular to the one-dimensional polymerization axis provide another element of long-range order, and electrostatic inter-actions with K+ ions provide connectivity between adjacent polymeric structures.
UR - http://www.scopus.com/inward/record.url?scp=68649094476&partnerID=8YFLogxK
U2 - 10.1107/S010827010902839X
DO - 10.1107/S010827010902839X
M3 - Article
AN - SCOPUS:68649094476
SN - 0108-2701
VL - 65
SP - m328-m330
JO - Acta Crystallographica Section C: Crystal Structure Communications
JF - Acta Crystallographica Section C: Crystal Structure Communications
IS - 8
ER -