Syntheses and structures of new blue luminescent B(III) and Al(III) complexes: BPh2(acac-azain) and Al(CH3)(acac-azain)2, acac-azain=1-N-7-azaindolyl-1,3-butanedionato

Datong Song; Shi Feng Liu; Rui Yao Wang; Suning Wang

doi:10.1016/S0022-328X(01)01017-8

Syntheses and structures of new blue luminescent B(III) and Al(III) complexes: BPh₂(acac-azain) and Al(CH₃)(acac-azain)₂, acac-azain=1-N-7-azaindolyl-1,3-butanedionato

Datong Song^*, Shi Feng Liu, Rui Yao Wang, Suning Wang

^*Corresponding author for this work

Queen's University Kingston

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

A novel blue luminescent ligand, 1-N-7-azaindolyl-1,3-butanedione (acac-azainH), has been synthesized and characterized structurally. The acac-azainH has a diketone structure in the solid state. The diketone form of acac-azainH is also dominant in solution. The acac-azainH molecule reacts readily with BPh₃ and Al(CH₃)₃ to form chelate complexes BPh₂(acac-azain) (1) and Al(CH₃)(acac-azain)₂ (2), respectively. The structure of 1 was determined by a single-crystal X-ray diffraction analysis. The acac-azainH molecule and compounds 1 and 2 are all blue luminescent but the luminescent efficiency is poor. In solution, compound 2 appears to exist in two isomeric forms.

Original language	English
Pages (from-to)	175-180
Number of pages	6
Journal	Journal of Organometallic Chemistry
Volume	631
Issue number	1-2
DOIs	https://doi.org/10.1016/S0022-328X(01)01017-8
Publication status	Published - 10 Aug 2001
Externally published	Yes

Keywords

Aluminum
Azaindolyl
Boron
Luminescence

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10.1016/S0022-328X(01)01017-8

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@article{c76812bb72bc49b4ae7229f373919688,

title = "Syntheses and structures of new blue luminescent B(III) and Al(III) complexes: BPh2(acac-azain) and Al(CH3)(acac-azain)2, acac-azain=1-N-7-azaindolyl-1,3-butanedionato",

abstract = "A novel blue luminescent ligand, 1-N-7-azaindolyl-1,3-butanedione (acac-azainH), has been synthesized and characterized structurally. The acac-azainH has a diketone structure in the solid state. The diketone form of acac-azainH is also dominant in solution. The acac-azainH molecule reacts readily with BPh3 and Al(CH3)3 to form chelate complexes BPh2(acac-azain) (1) and Al(CH3)(acac-azain)2 (2), respectively. The structure of 1 was determined by a single-crystal X-ray diffraction analysis. The acac-azainH molecule and compounds 1 and 2 are all blue luminescent but the luminescent efficiency is poor. In solution, compound 2 appears to exist in two isomeric forms.",

keywords = "Aluminum, Azaindolyl, Boron, Luminescence",

author = "Datong Song and Liu, {Shi Feng} and Wang, {Rui Yao} and Suning Wang",

note = "Funding Information: We thank the Natural Sciences and Engineering Research Council of Canada and the Xerox Research Foundation for financial support. ",

year = "2001",

month = aug,

day = "10",

doi = "10.1016/S0022-328X(01)01017-8",

language = "English",

volume = "631",

pages = "175--180",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

number = "1-2",

}

Syntheses and structures of new blue luminescent B(III) and Al(III) complexes: BPh₂(acac-azain) and Al(CH₃)(acac-azain)₂, acac-azain=1-N-7-azaindolyl-1,3-butanedionato. / Song, Datong; Liu, Shi Feng; Wang, Rui Yao et al.
In: Journal of Organometallic Chemistry, Vol. 631, No. 1-2, 10.08.2001, p. 175-180.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Syntheses and structures of new blue luminescent B(III) and Al(III) complexes

T2 - BPh2(acac-azain) and Al(CH3)(acac-azain)2, acac-azain=1-N-7-azaindolyl-1,3-butanedionato

AU - Song, Datong

AU - Liu, Shi Feng

AU - Wang, Rui Yao

AU - Wang, Suning

N1 - Funding Information: We thank the Natural Sciences and Engineering Research Council of Canada and the Xerox Research Foundation for financial support.

PY - 2001/8/10

Y1 - 2001/8/10

N2 - A novel blue luminescent ligand, 1-N-7-azaindolyl-1,3-butanedione (acac-azainH), has been synthesized and characterized structurally. The acac-azainH has a diketone structure in the solid state. The diketone form of acac-azainH is also dominant in solution. The acac-azainH molecule reacts readily with BPh3 and Al(CH3)3 to form chelate complexes BPh2(acac-azain) (1) and Al(CH3)(acac-azain)2 (2), respectively. The structure of 1 was determined by a single-crystal X-ray diffraction analysis. The acac-azainH molecule and compounds 1 and 2 are all blue luminescent but the luminescent efficiency is poor. In solution, compound 2 appears to exist in two isomeric forms.

AB - A novel blue luminescent ligand, 1-N-7-azaindolyl-1,3-butanedione (acac-azainH), has been synthesized and characterized structurally. The acac-azainH has a diketone structure in the solid state. The diketone form of acac-azainH is also dominant in solution. The acac-azainH molecule reacts readily with BPh3 and Al(CH3)3 to form chelate complexes BPh2(acac-azain) (1) and Al(CH3)(acac-azain)2 (2), respectively. The structure of 1 was determined by a single-crystal X-ray diffraction analysis. The acac-azainH molecule and compounds 1 and 2 are all blue luminescent but the luminescent efficiency is poor. In solution, compound 2 appears to exist in two isomeric forms.

KW - Aluminum

KW - Azaindolyl

KW - Boron

KW - Luminescence

UR - http://www.scopus.com/inward/record.url?scp=0010546943&partnerID=8YFLogxK

U2 - 10.1016/S0022-328X(01)01017-8

DO - 10.1016/S0022-328X(01)01017-8

M3 - Article

AN - SCOPUS:0010546943

SN - 0022-328X

VL - 631

SP - 175

EP - 180

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1-2

ER -

Syntheses and structures of new blue luminescent B(III) and Al(III) complexes: BPh₂(acac-azain) and Al(CH₃)(acac-azain)₂, acac-azain=1-N-7-azaindolyl-1,3-butanedionato

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