Self-assembly of one-dimensional coordination polymers from M(II) salts (M=Co, Cd) and flexible ligand 1,3-bis(4-pyridyl)propane

Mary T. Bujaci; Xiaotai Wang; Shoujian Li; Chong Zheng

doi:10.1016/S0020-1693(02)00816-2

Self-assembly of one-dimensional coordination polymers from M(II) salts (M=Co, Cd) and flexible ligand 1,3-bis(4-pyridyl)propane

Mary T. Bujaci, Xiaotai Wang^*, Shoujian Li, Chong Zheng

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

38 Citations (Scopus)

Abstract

Reaction of Co(NO₃)₂ or Cd(NO₃) ₂ with 1,3-bis(4-pyridyl)propane (or bpp) in a mixture of benzene and methanol generates one-dimensional (1-D) coordination polymers [Co(bpp) ₂(NO₃)₂]·2C₆H₆ (1) and [Cd(bpp)₂(NO₃)₂]·2C ₆H₆ (2). The isostructural 1 and 2 crystallize in monoclinic space group P1̄. The polymeric framework in 1 or 2 is neutral in which the metal ions have an octahedral geometry and are bridged by two bpp ligands. The six-coordination of Co(II) or Cd(II) is satisfied by its binding two nitrate ions in addition to the four pyridyl nitrogen atoms from four different bpp ligands.

Original language	English
Pages (from-to)	152-154
Number of pages	3
Journal	Inorganica Chimica Acta
Volume	333
Issue number	1
DOIs	https://doi.org/10.1016/S0020-1693(02)00816-2
Publication status	Published - 15 May 2002
Externally published	Yes

Keywords

Cadmium complexes
Cobalt complexes
Coordination polymers
Crystal structures

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10.1016/S0020-1693(02)00816-2

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@article{1cb31824b197462e8491429725f8558c,

title = "Self-assembly of one-dimensional coordination polymers from M(II) salts (M=Co, Cd) and flexible ligand 1,3-bis(4-pyridyl)propane",

abstract = "Reaction of Co(NO3)2 or Cd(NO3) 2 with 1,3-bis(4-pyridyl)propane (or bpp) in a mixture of benzene and methanol generates one-dimensional (1-D) coordination polymers [Co(bpp) 2(NO3)2]·2C6H6 (1) and [Cd(bpp)2(NO3)2]·2C 6H6 (2). The isostructural 1 and 2 crystallize in monoclinic space group P{\=1}. The polymeric framework in 1 or 2 is neutral in which the metal ions have an octahedral geometry and are bridged by two bpp ligands. The six-coordination of Co(II) or Cd(II) is satisfied by its binding two nitrate ions in addition to the four pyridyl nitrogen atoms from four different bpp ligands.",

keywords = "Cadmium complexes, Cobalt complexes, Coordination polymers, Crystal structures",

author = "Bujaci, {Mary T.} and Xiaotai Wang and Shoujian Li and Chong Zheng",

note = "Funding Information: This work was supported by the University of Colorado at Denver and Research Corporation.",

year = "2002",

month = may,

day = "15",

doi = "10.1016/S0020-1693(02)00816-2",

language = "English",

volume = "333",

pages = "152--154",

journal = "Inorganica Chimica Acta",

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TY - JOUR

T1 - Self-assembly of one-dimensional coordination polymers from M(II) salts (M=Co, Cd) and flexible ligand 1,3-bis(4-pyridyl)propane

AU - Bujaci, Mary T.

AU - Wang, Xiaotai

AU - Li, Shoujian

AU - Zheng, Chong

N1 - Funding Information: This work was supported by the University of Colorado at Denver and Research Corporation.

PY - 2002/5/15

Y1 - 2002/5/15

N2 - Reaction of Co(NO3)2 or Cd(NO3) 2 with 1,3-bis(4-pyridyl)propane (or bpp) in a mixture of benzene and methanol generates one-dimensional (1-D) coordination polymers [Co(bpp) 2(NO3)2]·2C6H6 (1) and [Cd(bpp)2(NO3)2]·2C 6H6 (2). The isostructural 1 and 2 crystallize in monoclinic space group P1̄. The polymeric framework in 1 or 2 is neutral in which the metal ions have an octahedral geometry and are bridged by two bpp ligands. The six-coordination of Co(II) or Cd(II) is satisfied by its binding two nitrate ions in addition to the four pyridyl nitrogen atoms from four different bpp ligands.

AB - Reaction of Co(NO3)2 or Cd(NO3) 2 with 1,3-bis(4-pyridyl)propane (or bpp) in a mixture of benzene and methanol generates one-dimensional (1-D) coordination polymers [Co(bpp) 2(NO3)2]·2C6H6 (1) and [Cd(bpp)2(NO3)2]·2C 6H6 (2). The isostructural 1 and 2 crystallize in monoclinic space group P1̄. The polymeric framework in 1 or 2 is neutral in which the metal ions have an octahedral geometry and are bridged by two bpp ligands. The six-coordination of Co(II) or Cd(II) is satisfied by its binding two nitrate ions in addition to the four pyridyl nitrogen atoms from four different bpp ligands.

KW - Cadmium complexes

KW - Cobalt complexes

KW - Coordination polymers

KW - Crystal structures

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U2 - 10.1016/S0020-1693(02)00816-2

DO - 10.1016/S0020-1693(02)00816-2

M3 - Article

AN - SCOPUS:0037094303

SN - 0020-1693

VL - 333

SP - 152

EP - 154

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 1

ER -

Self-assembly of one-dimensional coordination polymers from M(II) salts (M=Co, Cd) and flexible ligand 1,3-bis(4-pyridyl)propane

Abstract

Keywords

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