Rhodium N-heterocyclic carbene carboxylato complexes: Synthesis, structure determination, and catalytic activity in the hydroformylation of alkenes

Jeremy M. Praetorius; Matthew W. Kotyk; Jonathan D. Webb; Ruiyao Wang; Cathleen M. Crudden

doi:10.1021/om060942y

Rhodium N-heterocyclic carbene carboxylato complexes: Synthesis, structure determination, and catalytic activity in the hydroformylation of alkenes

Jeremy M. Praetorius, Matthew W. Kotyk, Jonathan D. Webb, Ruiyao Wang, Cathleen M. Crudden^*

^*Corresponding author for this work

Queen's University Kingston

Research output: Contribution to journal › Article › peer-review

48 Citations (Scopus)

Abstract

Rhodium carboxylato complexes bearing N-heterocyclic carbene ligands, [Rh(IPr)(CO)₂(OAc)] (1) and [Rh(IPr)₂(CO)(OAc)J (2), have been synthesized and characterized. The two complexes are catalytically active for the regioselective hydroformylation of both aryl and aliphatic alkenes with regioselectivities of up to 40:1, without concomitant isomerization or hydrogenation.

Original language	English
Pages (from-to)	1057-1061
Number of pages	5
Journal	Organometallics
Volume	26
Issue number	4
DOIs	https://doi.org/10.1021/om060942y
Publication status	Published - 12 Feb 2007
Externally published	Yes

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abstract = "Rhodium carboxylato complexes bearing N-heterocyclic carbene ligands, [Rh(IPr)(CO)2(OAc)] (1) and [Rh(IPr)2(CO)(OAc)J (2), have been synthesized and characterized. The two complexes are catalytically active for the regioselective hydroformylation of both aryl and aliphatic alkenes with regioselectivities of up to 40:1, without concomitant isomerization or hydrogenation.",

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T2 - Synthesis, structure determination, and catalytic activity in the hydroformylation of alkenes

AU - Praetorius, Jeremy M.

AU - Kotyk, Matthew W.

AU - Webb, Jonathan D.

AU - Wang, Ruiyao

AU - Crudden, Cathleen M.

PY - 2007/2/12

Y1 - 2007/2/12

N2 - Rhodium carboxylato complexes bearing N-heterocyclic carbene ligands, [Rh(IPr)(CO)2(OAc)] (1) and [Rh(IPr)2(CO)(OAc)J (2), have been synthesized and characterized. The two complexes are catalytically active for the regioselective hydroformylation of both aryl and aliphatic alkenes with regioselectivities of up to 40:1, without concomitant isomerization or hydrogenation.

AB - Rhodium carboxylato complexes bearing N-heterocyclic carbene ligands, [Rh(IPr)(CO)2(OAc)] (1) and [Rh(IPr)2(CO)(OAc)J (2), have been synthesized and characterized. The two complexes are catalytically active for the regioselective hydroformylation of both aryl and aliphatic alkenes with regioselectivities of up to 40:1, without concomitant isomerization or hydrogenation.

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JO - Organometallics

JF - Organometallics

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ER -

Rhodium N-heterocyclic carbene carboxylato complexes: Synthesis, structure determination, and catalytic activity in the hydroformylation of alkenes

Abstract

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