Luminescent triarylboron-functionalized zinc carboxylate metal-organic framework

Barry A. Blight; Rémy Guillet-Nicolas; Freddy Kleitz; Rui Yao Wang; Suning Wang

doi:10.1021/ic3020223

Luminescent triarylboron-functionalized zinc carboxylate metal-organic framework

Barry A. Blight, Rémy Guillet-Nicolas, Freddy Kleitz^*, Rui Yao Wang, Suning Wang

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

54 Citations (Scopus)

Abstract

A luminescent triarylboron ligand functionalized with three carboxylic groups has been synthesized and fully characterized. Its use in boron-containing metal-organic frameworks (B-MOFs) has been demonstrated by the synthesis and isolation of a Zn^IIB-MOF compound (B-MOF-1). The crystals of B-MOF-1 belong to the cubic space group F432 with 8-fold interpenetrated networks and ∼21% void space. B-MOF-1 exhibits blue fluorescence and is capable of modest gas sorption of N₂, argon, and CO₂.

Original language	English
Pages (from-to)	1673-1675
Number of pages	3
Journal	Inorganic Chemistry
Volume	52
Issue number	4
DOIs	https://doi.org/10.1021/ic3020223
Publication status	Published - 18 Feb 2013
Externally published	Yes

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title = "Luminescent triarylboron-functionalized zinc carboxylate metal-organic framework",

abstract = "A luminescent triarylboron ligand functionalized with three carboxylic groups has been synthesized and fully characterized. Its use in boron-containing metal-organic frameworks (B-MOFs) has been demonstrated by the synthesis and isolation of a ZnIIB-MOF compound (B-MOF-1). The crystals of B-MOF-1 belong to the cubic space group F432 with 8-fold interpenetrated networks and ∼21% void space. B-MOF-1 exhibits blue fluorescence and is capable of modest gas sorption of N2, argon, and CO2.",

author = "Blight, {Barry A.} and R{\'e}my Guillet-Nicolas and Freddy Kleitz and Wang, {Rui Yao} and Suning Wang",

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doi = "10.1021/ic3020223",

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journal = "Inorganic Chemistry",

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T1 - Luminescent triarylboron-functionalized zinc carboxylate metal-organic framework

AU - Blight, Barry A.

AU - Guillet-Nicolas, Rémy

AU - Kleitz, Freddy

AU - Wang, Rui Yao

AU - Wang, Suning

PY - 2013/2/18

Y1 - 2013/2/18

N2 - A luminescent triarylboron ligand functionalized with three carboxylic groups has been synthesized and fully characterized. Its use in boron-containing metal-organic frameworks (B-MOFs) has been demonstrated by the synthesis and isolation of a ZnIIB-MOF compound (B-MOF-1). The crystals of B-MOF-1 belong to the cubic space group F432 with 8-fold interpenetrated networks and ∼21% void space. B-MOF-1 exhibits blue fluorescence and is capable of modest gas sorption of N2, argon, and CO2.

AB - A luminescent triarylboron ligand functionalized with three carboxylic groups has been synthesized and fully characterized. Its use in boron-containing metal-organic frameworks (B-MOFs) has been demonstrated by the synthesis and isolation of a ZnIIB-MOF compound (B-MOF-1). The crystals of B-MOF-1 belong to the cubic space group F432 with 8-fold interpenetrated networks and ∼21% void space. B-MOF-1 exhibits blue fluorescence and is capable of modest gas sorption of N2, argon, and CO2.

UR - http://www.scopus.com/inward/record.url?scp=84874041136&partnerID=8YFLogxK

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M3 - Article

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VL - 52

SP - 1673

EP - 1675

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 4

ER -

Luminescent triarylboron-functionalized zinc carboxylate metal-organic framework

Abstract

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