Luminescent 2D macrocyclic networks based on starburst molecules: [{Ag(CF3SO3)}1.5(tdapb)] and [{Ag(NO 3)}3(tdapb)]

Corey Seward, Wen Li Jia, Rui Yao Wang, Gary D. Enright, Suning Wang*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

165 Citations (Scopus)

Abstract

The impact of the anion on the assembly of extended 2D structures has been demonstrated by two distinct luminescent 2D lattices. Shown here is the macrocyclic cloverleaf-shaped cavity obtained from the reaction of a starburst ligand with Ag(NO3). Use of the triflate salt instead results in a honeycomb-shaped cavity.

Original languageEnglish
Pages (from-to)2933-2936
Number of pages4
JournalAngewandte Chemie - International Edition
Volume43
Issue number22
DOIs
Publication statusPublished - 24 May 2004
Externally publishedYes

Keywords

  • Luminescence
  • Macrocycles
  • N ligands
  • Silver
  • Supramolecular chemistry

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