Abstract
Dimeric rhodium N-heterocyclic carbene complexes are demonstrated to be effective catalyst precursors for directed C–H borylation reactions at room temperature. The reactions are highly selective for mono-borylation and can be combined with a one-pot Suzuki–Miyaura coupling to give C–H arylation products with exclusive selectivity for mono-arylation without the requirement for steric blocking groups.
Original language | English |
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Pages (from-to) | 9883-9886 |
Number of pages | 4 |
Journal | Chemical Communications |
Volume | 50 |
Issue number | 69 |
DOIs | |
Publication status | Published - 31 Jul 2014 |
Externally published | Yes |