Formation of an heterochiral supramolecular cage by diastereomer self-discrimination: Fluorescence enhancement and C60 sensing

Carlos Solano Arribas; Ola F. Wendt; Anders P. Sundin; Carl Johan Carling; Ruiyao Wang; Robert P. Lemieux; Kenneth Wärnmark

doi:10.1039/b927030b

Formation of an heterochiral supramolecular cage by diastereomer self-discrimination: Fluorescence enhancement and C₆₀ sensing

Carlos Solano Arribas, Ola F. Wendt, Anders P. Sundin, Carl Johan Carling, Ruiyao Wang, Robert P. Lemieux, Kenneth Wärnmark^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

27 Citations (Scopus)

Abstract

Diastereomer discrimination was observed in the formation of a metallomacrocycle from a racemic ligand based on Tröger's base. The metallomacrocycle exhibited a dramatic increase in fluorescence intensity compared to the ligand and its fluorescence was efficiently quenched by C ₆₀.

Original language	English
Pages (from-to)	4381-4383
Number of pages	3
Journal	Chemical Communications
Volume	46
Issue number	24
DOIs	https://doi.org/10.1039/b927030b
Publication status	Published - 2010
Externally published	Yes

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10.1039/b927030b

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title = "Formation of an heterochiral supramolecular cage by diastereomer self-discrimination: Fluorescence enhancement and C60 sensing",

abstract = "Diastereomer discrimination was observed in the formation of a metallomacrocycle from a racemic ligand based on Tr{\"o}ger's base. The metallomacrocycle exhibited a dramatic increase in fluorescence intensity compared to the ligand and its fluorescence was efficiently quenched by C 60.",

author = "Arribas, {Carlos Solano} and Wendt, {Ola F.} and Sundin, {Anders P.} and Carling, {Carl Johan} and Ruiyao Wang and Lemieux, {Robert P.} and Kenneth W{\"a}rnmark",

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T2 - Fluorescence enhancement and C60 sensing

AU - Arribas, Carlos Solano

AU - Wendt, Ola F.

AU - Sundin, Anders P.

AU - Carling, Carl Johan

AU - Wang, Ruiyao

AU - Lemieux, Robert P.

AU - Wärnmark, Kenneth

PY - 2010

Y1 - 2010

N2 - Diastereomer discrimination was observed in the formation of a metallomacrocycle from a racemic ligand based on Tröger's base. The metallomacrocycle exhibited a dramatic increase in fluorescence intensity compared to the ligand and its fluorescence was efficiently quenched by C 60.

AB - Diastereomer discrimination was observed in the formation of a metallomacrocycle from a racemic ligand based on Tröger's base. The metallomacrocycle exhibited a dramatic increase in fluorescence intensity compared to the ligand and its fluorescence was efficiently quenched by C 60.

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U2 - 10.1039/b927030b

DO - 10.1039/b927030b

M3 - Article

C2 - 20473442

AN - SCOPUS:77953307037

SN - 1359-7345

VL - 46

SP - 4381

EP - 4383

JO - Chemical Communications

JF - Chemical Communications

IS - 24

ER -

Formation of an heterochiral supramolecular cage by diastereomer self-discrimination: Fluorescence enhancement and C60 sensing

Abstract

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Formation of an heterochiral supramolecular cage by diastereomer self-discrimination: Fluorescence enhancement and C₆₀ sensing