A new porous three-dimensional lanthanide coordination polymer

Long Pan, E. Brice Woodlock, Xiaotai Wang*, Chong Zheng

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

185 Citations (Scopus)

Abstract

The open-framework coordination polymer [Er(C9H9-O6)(H2O)2]·2.5H2O (C9H9O6 = cis,cis-1,3,5-cyclohexanetricarboxylate) has been synthesized under hydrothermal conditions. Each Er ion is coordinated to nine oxygen atoms belonging to two water molecules and five carboxylate ligands. Its 3-D polymeric structure possesses channels containing the guest water molecules that can be removed to afford a porous material [Er(C9H9O6)(H2O)2]. The metalorganic framework in [Er(C9H9O6)(H2O)2] can withstand the removal of 1 equiv of coordinated water.

Original languageEnglish
Pages (from-to)4174-4178
Number of pages5
JournalInorganic Chemistry
Volume39
Issue number18
DOIs
Publication statusPublished - 4 Sept 2000
Externally publishedYes

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