1-D infinite array of metalloporphyrin cages

Long Pan; Xiaoying Huang; Hoa Loan N. Phan; T. J. Emge; Jing Li; Xiaotai Wang

doi:10.1021/ic049141i

1-D infinite array of metalloporphyrin cages

Long Pan, Xiaoying Huang, Hoa Loan N. Phan, T. J. Emge, Jing Li^*, Xiaotai Wang

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

38 Citations (Scopus)

Abstract

The reaction of Co(II) with 5,15-dipyridyl-10,20-diphenylporphyrin (H ₂DPyP) produces the first metal-organic coordination polymer supported by a trans meso-bifunctional porphyrin ligand. Formulated empirically as [Co₃(DPyP)₃]·4HDMF, this compound exhibits a ribbonlike coordination network consisting of tetranuclear metalloporphyrin cages. The DMF guest molecules fill the intra-ribbon cages as well as the inter-ribbon space. Evacuation of [Co₃(DPyP)₃]·4DMF at 130 °C generates [Co₃(DPyP)₃] that retains crystallinity, as shown by its powder X-ray diffraction pattern, which is consistent with that of [Co₃(DPyP)₃·4HDMF.

Original language	English
Pages (from-to)	6878-6880
Number of pages	3
Journal	Inorganic Chemistry
Volume	43
Issue number	22
DOIs	https://doi.org/10.1021/ic049141i
Publication status	Published - 1 Nov 2004
Externally published	Yes

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title = "1-D infinite array of metalloporphyrin cages",

abstract = "The reaction of Co(II) with 5,15-dipyridyl-10,20-diphenylporphyrin (H 2DPyP) produces the first metal-organic coordination polymer supported by a trans meso-bifunctional porphyrin ligand. Formulated empirically as [Co3(DPyP)3]·4HDMF, this compound exhibits a ribbonlike coordination network consisting of tetranuclear metalloporphyrin cages. The DMF guest molecules fill the intra-ribbon cages as well as the inter-ribbon space. Evacuation of [Co3(DPyP)3]·4DMF at 130 °C generates [Co3(DPyP)3] that retains crystallinity, as shown by its powder X-ray diffraction pattern, which is consistent with that of [Co3(DPyP)3·4HDMF.",

author = "Long Pan and Xiaoying Huang and Phan, {Hoa Loan N.} and Emge, {T. J.} and Jing Li and Xiaotai Wang",

year = "2004",

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doi = "10.1021/ic049141i",

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T1 - 1-D infinite array of metalloporphyrin cages

AU - Pan, Long

AU - Huang, Xiaoying

AU - Phan, Hoa Loan N.

AU - Emge, T. J.

AU - Li, Jing

AU - Wang, Xiaotai

PY - 2004/11/1

Y1 - 2004/11/1

N2 - The reaction of Co(II) with 5,15-dipyridyl-10,20-diphenylporphyrin (H 2DPyP) produces the first metal-organic coordination polymer supported by a trans meso-bifunctional porphyrin ligand. Formulated empirically as [Co3(DPyP)3]·4HDMF, this compound exhibits a ribbonlike coordination network consisting of tetranuclear metalloporphyrin cages. The DMF guest molecules fill the intra-ribbon cages as well as the inter-ribbon space. Evacuation of [Co3(DPyP)3]·4DMF at 130 °C generates [Co3(DPyP)3] that retains crystallinity, as shown by its powder X-ray diffraction pattern, which is consistent with that of [Co3(DPyP)3·4HDMF.

AB - The reaction of Co(II) with 5,15-dipyridyl-10,20-diphenylporphyrin (H 2DPyP) produces the first metal-organic coordination polymer supported by a trans meso-bifunctional porphyrin ligand. Formulated empirically as [Co3(DPyP)3]·4HDMF, this compound exhibits a ribbonlike coordination network consisting of tetranuclear metalloporphyrin cages. The DMF guest molecules fill the intra-ribbon cages as well as the inter-ribbon space. Evacuation of [Co3(DPyP)3]·4DMF at 130 °C generates [Co3(DPyP)3] that retains crystallinity, as shown by its powder X-ray diffraction pattern, which is consistent with that of [Co3(DPyP)3·4HDMF.

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U2 - 10.1021/ic049141i

DO - 10.1021/ic049141i

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SP - 6878

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JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 22

ER -

1-D infinite array of metalloporphyrin cages

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