Three-component reactions leading to 2D and 3D metal-organic frameworks assembled on dinickel-carboxylate secondary building units

Anjian Lan; Lian Chen; Daqiang Yuan; Yougui Huang; Maochun Hong; Xiaotai Wang

doi:10.1016/j.poly.2010.09.026

Three-component reactions leading to 2D and 3D metal-organic frameworks assembled on dinickel-carboxylate secondary building units

Anjian Lan
, Lian Chen
, Daqiang Yuan
, Yougui Huang
, Maochun Hong
, Xiaotai Wang^*

^*Corresponding author for this work

CAS - Fujian Institute of Research on the Structure of Matter
University of Colorado Denver

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

Three-component reactions involving Ni(II) ions and dicarboxylate and bipyridyl ligands under hydrothermal conditions produce two novel metal-organic coordination polymers formulated empirically as [Ni(PDA)(BPE)] (1) and [Ni ₂(PDA)₂(BPP)(H₂O)]·2.5H₂O (2), where PDA = 1,4-phenylenediacetate, BPE = 1,2-bis(4-pyridyl)ethane, and BPP = 1,3-bis(4-pyridyl)propane. Both compounds possess 2D or 3D metal-organic frameworks (MOFs) that are assembled on dinickel-carboxylate secondary building units. Compound 1 has a condensed 3D MOF, whereas 2 contains void between 2D MOFs where guest water molecules reside. Both compounds demonstrate antiferromagnetic coupling between Ni(II) ions.

Original language	English
Pages (from-to)	47-52
Number of pages	6
Journal	Polyhedron
Volume	30
Issue number	1
DOIs	https://doi.org/10.1016/j.poly.2010.09.026
Publication status	Published - 12 Jan 2011
Externally published	Yes

Keywords

Coordination polymers
Metal-organic frameworks
Nickel(II) complexes
Secondary building units
Three-component reactions

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10.1016/j.poly.2010.09.026

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@article{38946446cc2d4f3b9a8418a2ac90faf4,

title = "Three-component reactions leading to 2D and 3D metal-organic frameworks assembled on dinickel-carboxylate secondary building units",

abstract = "Three-component reactions involving Ni(II) ions and dicarboxylate and bipyridyl ligands under hydrothermal conditions produce two novel metal-organic coordination polymers formulated empirically as [Ni(PDA)(BPE)] (1) and [Ni 2(PDA)2(BPP)(H2O)]·2.5H2O (2), where PDA = 1,4-phenylenediacetate, BPE = 1,2-bis(4-pyridyl)ethane, and BPP = 1,3-bis(4-pyridyl)propane. Both compounds possess 2D or 3D metal-organic frameworks (MOFs) that are assembled on dinickel-carboxylate secondary building units. Compound 1 has a condensed 3D MOF, whereas 2 contains void between 2D MOFs where guest water molecules reside. Both compounds demonstrate antiferromagnetic coupling between Ni(II) ions.",

keywords = "Coordination polymers, Metal-organic frameworks, Nickel(II) complexes, Secondary building units, Three-component reactions",

author = "Anjian Lan and Lian Chen and Daqiang Yuan and Yougui Huang and Maochun Hong and Xiaotai Wang",

note = "Funding Information: The authors gratefully acknowledge support for this work from the donors of The Petroleum Research Fund , administrated by the ACS; Research Corporation ; and the Chinese Academy of Sciences . Lan is thankful for a grant from the National Natural Science Foundation of China ( 21071144 ). ",

year = "2011",

month = jan,

day = "12",

doi = "10.1016/j.poly.2010.09.026",

language = "English",

volume = "30",

pages = "47--52",

journal = "Polyhedron",

issn = "0277-5387",

number = "1",

}

TY - JOUR

T1 - Three-component reactions leading to 2D and 3D metal-organic frameworks assembled on dinickel-carboxylate secondary building units

AU - Lan, Anjian

AU - Chen, Lian

AU - Yuan, Daqiang

AU - Huang, Yougui

AU - Hong, Maochun

AU - Wang, Xiaotai

N1 - Funding Information: The authors gratefully acknowledge support for this work from the donors of The Petroleum Research Fund , administrated by the ACS; Research Corporation ; and the Chinese Academy of Sciences . Lan is thankful for a grant from the National Natural Science Foundation of China ( 21071144 ).

PY - 2011/1/12

Y1 - 2011/1/12

N2 - Three-component reactions involving Ni(II) ions and dicarboxylate and bipyridyl ligands under hydrothermal conditions produce two novel metal-organic coordination polymers formulated empirically as [Ni(PDA)(BPE)] (1) and [Ni 2(PDA)2(BPP)(H2O)]·2.5H2O (2), where PDA = 1,4-phenylenediacetate, BPE = 1,2-bis(4-pyridyl)ethane, and BPP = 1,3-bis(4-pyridyl)propane. Both compounds possess 2D or 3D metal-organic frameworks (MOFs) that are assembled on dinickel-carboxylate secondary building units. Compound 1 has a condensed 3D MOF, whereas 2 contains void between 2D MOFs where guest water molecules reside. Both compounds demonstrate antiferromagnetic coupling between Ni(II) ions.

AB - Three-component reactions involving Ni(II) ions and dicarboxylate and bipyridyl ligands under hydrothermal conditions produce two novel metal-organic coordination polymers formulated empirically as [Ni(PDA)(BPE)] (1) and [Ni 2(PDA)2(BPP)(H2O)]·2.5H2O (2), where PDA = 1,4-phenylenediacetate, BPE = 1,2-bis(4-pyridyl)ethane, and BPP = 1,3-bis(4-pyridyl)propane. Both compounds possess 2D or 3D metal-organic frameworks (MOFs) that are assembled on dinickel-carboxylate secondary building units. Compound 1 has a condensed 3D MOF, whereas 2 contains void between 2D MOFs where guest water molecules reside. Both compounds demonstrate antiferromagnetic coupling between Ni(II) ions.

KW - Coordination polymers

KW - Metal-organic frameworks

KW - Nickel(II) complexes

KW - Secondary building units

KW - Three-component reactions

UR - https://www.scopus.com/pages/publications/78650839232

U2 - 10.1016/j.poly.2010.09.026

DO - 10.1016/j.poly.2010.09.026

M3 - Article

AN - SCOPUS:78650839232

SN - 0277-5387

VL - 30

SP - 47

EP - 52

JO - Polyhedron

JF - Polyhedron

IS - 1

ER -

Three-component reactions leading to 2D and 3D metal-organic frameworks assembled on dinickel-carboxylate secondary building units

Abstract

Keywords

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