The anionic coordination polymer {K2[PtII 2AgI8(2,2′-bipyridine)2(O 2CCF3)14]}n

Zachary M. Hudson; Yi Sun; Bryan Ross; Rui Yao Wang; Suning Wang

doi:10.1107/S010827010902839X

The anionic coordination polymer {K₂[Pt^II ₂Ag^I₈(2,2′-bipyridine)₂(O ₂CCF₃)₁₄]}_n

Zachary M. Hudson
, Yi Sun
, Bryan Ross
, Rui Yao Wang
, Suning Wang^*

^*Corresponding author for this work

Queen's University Kingston

Research output: Contribution to journal › Article › peer-review

Abstract

The trimetallic compound catena-poly[dipotassium(I) [bis-(2,2′- bipyridine)di-μ₃-trifluoro-acetato-dodeca-2-trifluoro-acetato- diplatinum(II)octa-silver(I)]], K₂ [Pt₂Ag₈ (C₂F₃O₂)₁₄(C₁₀H ₈N₂)₂], forms an extended structure in the solid state. Electrostatic inter-actions involving the K⁺ ions play a key role in the formation of the extended structure in three dimensions. The Ag^I ions form one-dimensional coordination polymers, with alternating Ag₂ and Ag₆ units linked by CF₃CO₂ ^- ligands. Pt⋯Pt inter-actions perpendicular to the one-dimensional polymerization axis provide another element of long-range order, and electrostatic inter-actions with K⁺ ions provide connectivity between adjacent polymeric structures.

Original language	English
Pages (from-to)	m328-m330
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	65
Issue number	8
DOIs	https://doi.org/10.1107/S010827010902839X
Publication status	Published - 2009
Externally published	Yes

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title = "The anionic coordination polymer \{K2[PtII 2AgI8(2,2′-bipyridine)2(O 2CCF3)14]\}n",

abstract = "The trimetallic compound catena-poly[dipotassium(I) [bis-(2,2′- bipyridine)di-μ3-trifluoro-acetato-dodeca-2-trifluoro-acetato- diplatinum(II)octa-silver(I)]], K2 [Pt2Ag8 (C2F3O2)14(C10H 8N2)2], forms an extended structure in the solid state. Electrostatic inter-actions involving the K+ ions play a key role in the formation of the extended structure in three dimensions. The AgI ions form one-dimensional coordination polymers, with alternating Ag2 and Ag6 units linked by CF3CO2 - ligands. Pt⋯Pt inter-actions perpendicular to the one-dimensional polymerization axis provide another element of long-range order, and electrostatic inter-actions with K+ ions provide connectivity between adjacent polymeric structures.",

author = "Hudson, \{Zachary M.\} and Yi Sun and Bryan Ross and Wang, \{Rui Yao\} and Suning Wang",

year = "2009",

doi = "10.1107/S010827010902839X",

language = "English",

volume = "65",

pages = "m328--m330",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

number = "8",

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T1 - The anionic coordination polymer {K2[PtII 2AgI8(2,2′-bipyridine)2(O 2CCF3)14]}n

AU - Hudson, Zachary M.

AU - Sun, Yi

AU - Ross, Bryan

AU - Wang, Rui Yao

AU - Wang, Suning

PY - 2009

Y1 - 2009

N2 - The trimetallic compound catena-poly[dipotassium(I) [bis-(2,2′- bipyridine)di-μ3-trifluoro-acetato-dodeca-2-trifluoro-acetato- diplatinum(II)octa-silver(I)]], K2 [Pt2Ag8 (C2F3O2)14(C10H 8N2)2], forms an extended structure in the solid state. Electrostatic inter-actions involving the K+ ions play a key role in the formation of the extended structure in three dimensions. The AgI ions form one-dimensional coordination polymers, with alternating Ag2 and Ag6 units linked by CF3CO2 - ligands. Pt⋯Pt inter-actions perpendicular to the one-dimensional polymerization axis provide another element of long-range order, and electrostatic inter-actions with K+ ions provide connectivity between adjacent polymeric structures.

AB - The trimetallic compound catena-poly[dipotassium(I) [bis-(2,2′- bipyridine)di-μ3-trifluoro-acetato-dodeca-2-trifluoro-acetato- diplatinum(II)octa-silver(I)]], K2 [Pt2Ag8 (C2F3O2)14(C10H 8N2)2], forms an extended structure in the solid state. Electrostatic inter-actions involving the K+ ions play a key role in the formation of the extended structure in three dimensions. The AgI ions form one-dimensional coordination polymers, with alternating Ag2 and Ag6 units linked by CF3CO2 - ligands. Pt⋯Pt inter-actions perpendicular to the one-dimensional polymerization axis provide another element of long-range order, and electrostatic inter-actions with K+ ions provide connectivity between adjacent polymeric structures.

UR - https://www.scopus.com/pages/publications/68649094476

U2 - 10.1107/S010827010902839X

DO - 10.1107/S010827010902839X

M3 - Article

AN - SCOPUS:68649094476

SN - 0108-2701

VL - 65

SP - m328-m330

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 8

ER -

The anionic coordination polymer {K₂[Pt^II ₂Ag^I₈(2,2′-bipyridine)₂(O ₂CCF₃)₁₄]}_n

Abstract

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