Synthesis and structure of silver and rhodium 1,2,3-triazol-5-ylidene mesoionic carbene complexes

Eric C. Keske; Olena V. Zenkina; Ruiyao Wang; Cathleen M. Crudden

doi:10.1021/om201104f

Synthesis and structure of silver and rhodium 1,2,3-triazol-5-ylidene mesoionic carbene complexes

Eric C. Keske, Olena V. Zenkina, Ruiyao Wang, Cathleen M. Crudden^*

^*Corresponding author for this work

Queen's University Kingston

Research output: Contribution to journal › Article › peer-review

93 Citations (Scopus)

Abstract

New mono- and bidentate 1,2,3-triazol-5-ylidene mesoionic carbene (MIC) ligands have been synthesized and reacted with silver oxide, forming cationic 1:2 and 2:2 Ag:MIC ([AgL ₂]Br and [Ag ₂L ₂] [Ag ₂Br ₄]) complexes, respectively. These complexes have been isolated and characterized. They were further found to be potent transmetalation agents toward rhodium, resulting in the preparation of mono- and bimetallic rhodium complexes. The reaction of the 2:2 Ag:L complex with [Rh(COD) ₂]BF ₄ results in the first reported example of a cationic bimetallic rhodium MIC complex. This complex was fully characterized, and its X-ray structure is reported. Interestingly, this complex exhibits various secondary noncovalent interactions in the solid state of the general type C-HX, where X = F, Cl.

Original language	English
Pages (from-to)	456-461
Number of pages	6
Journal	Organometallics
Volume	31
Issue number	1
DOIs	https://doi.org/10.1021/om201104f
Publication status	Published - 9 Jan 2012
Externally published	Yes

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title = "Synthesis and structure of silver and rhodium 1,2,3-triazol-5-ylidene mesoionic carbene complexes",

abstract = "New mono- and bidentate 1,2,3-triazol-5-ylidene mesoionic carbene (MIC) ligands have been synthesized and reacted with silver oxide, forming cationic 1:2 and 2:2 Ag:MIC ([AgL 2]Br and [Ag 2L 2] [Ag 2Br 4]) complexes, respectively. These complexes have been isolated and characterized. They were further found to be potent transmetalation agents toward rhodium, resulting in the preparation of mono- and bimetallic rhodium complexes. The reaction of the 2:2 Ag:L complex with [Rh(COD) 2]BF 4 results in the first reported example of a cationic bimetallic rhodium MIC complex. This complex was fully characterized, and its X-ray structure is reported. Interestingly, this complex exhibits various secondary noncovalent interactions in the solid state of the general type C-HX, where X = F, Cl.",

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T1 - Synthesis and structure of silver and rhodium 1,2,3-triazol-5-ylidene mesoionic carbene complexes

AU - Keske, Eric C.

AU - Zenkina, Olena V.

AU - Wang, Ruiyao

AU - Crudden, Cathleen M.

PY - 2012/1/9

Y1 - 2012/1/9

N2 - New mono- and bidentate 1,2,3-triazol-5-ylidene mesoionic carbene (MIC) ligands have been synthesized and reacted with silver oxide, forming cationic 1:2 and 2:2 Ag:MIC ([AgL 2]Br and [Ag 2L 2] [Ag 2Br 4]) complexes, respectively. These complexes have been isolated and characterized. They were further found to be potent transmetalation agents toward rhodium, resulting in the preparation of mono- and bimetallic rhodium complexes. The reaction of the 2:2 Ag:L complex with [Rh(COD) 2]BF 4 results in the first reported example of a cationic bimetallic rhodium MIC complex. This complex was fully characterized, and its X-ray structure is reported. Interestingly, this complex exhibits various secondary noncovalent interactions in the solid state of the general type C-HX, where X = F, Cl.

AB - New mono- and bidentate 1,2,3-triazol-5-ylidene mesoionic carbene (MIC) ligands have been synthesized and reacted with silver oxide, forming cationic 1:2 and 2:2 Ag:MIC ([AgL 2]Br and [Ag 2L 2] [Ag 2Br 4]) complexes, respectively. These complexes have been isolated and characterized. They were further found to be potent transmetalation agents toward rhodium, resulting in the preparation of mono- and bimetallic rhodium complexes. The reaction of the 2:2 Ag:L complex with [Rh(COD) 2]BF 4 results in the first reported example of a cationic bimetallic rhodium MIC complex. This complex was fully characterized, and its X-ray structure is reported. Interestingly, this complex exhibits various secondary noncovalent interactions in the solid state of the general type C-HX, where X = F, Cl.

UR - https://www.scopus.com/pages/publications/84863049920

U2 - 10.1021/om201104f

DO - 10.1021/om201104f

M3 - Article

AN - SCOPUS:84863049920

SN - 0276-7333

VL - 31

SP - 456

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JO - Organometallics

JF - Organometallics

IS - 1

ER -

Synthesis and structure of silver and rhodium 1,2,3-triazol-5-ylidene mesoionic carbene complexes

Abstract

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