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Synthesis and Crystal Structure of [Er(OH2)8](ClO4) · 3.5 (1,4-Diox.)· 2H2O

  • Zhang Huajie
  • , Wang Ruiyao
  • , Jin Tianzhu*
  • , Zhou Zhongyuan
  • , Zhou Xiangge
  • *Corresponding author for this work
  • Peking University
  • CAS - Chengdu Institute of Organic Chemistry

Research output: Contribution to journalArticlepeer-review

3 Citations (Scopus)

Abstract

The title complex was synthesized in aqueous solution, · and its crystal structure was determined by X-ray diffraction. The crystal is monoclinic, space group P21/n with a = 1.1243 (3) nm, 6 = 2.4853(2) nm, c = 1.2962(1) nm, β= 95.08(1)°, F =3.608(1) nm3, Z = 4, Dc = 1.757 g/cm3. Each of the erbium ion is coordinated by eight water molecules. The complex is of polymeric structure with the octaaqua erbium complex species connected by 1,4-dioxane moieties through hydrogen bonds.

Original languageEnglish
Pages (from-to)313-314
Number of pages2
JournalJournal of Rare Earths
Volume16
Issue number4
Publication statusPublished - 1998
Externally publishedYes

Keywords

  • Crystal structure
  • Dioxane
  • Erbium complex
  • Rare earths

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