Ordering and interaction of molecules encapsulated in carbon nanotubes

A. N. Khlobystov; K. Porfyrakis; D. A. Britz; M. Kanai; R. Scipioni; S. G. Lyapin; J. G. Wiltshire; A. Ardavan; D. Nguyen-Manh; R. J. Nicholas; D. G. Pettifor; T. J.S. Dennis; G. A.D. Briggs

doi:10.1179/174328413X13789824293425

Ordering and interaction of molecules encapsulated in carbon nanotubes

A. N. Khlobystov^*
, K. Porfyrakis
, D. A. Britz
, M. Kanai
, R. Scipioni
, S. G. Lyapin
, J. G. Wiltshire
, A. Ardavan
, D. Nguyen-Manh
, R. J. Nicholas
, D. G. Pettifor
, T. J.S. Dennis
, G. A.D. Briggs

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

A clear understanding of the interactions between the building blocks of self-assembled molecular materials is essential for rational design of functional nanostructures. Intermolecular interactions have been investigated for three different classes of fullerenes in single-walled carbon nanotubes (SWNTs); van der Waals molecule - molecule and molecule - SWNT interactions control the geometry of the molecular arrays inside nanotubes; electrostatic intermolecular forces influence the alignment of polar endohedral fullerenes M@C₈₂; and hydrogen bonding between functionalised fullerenes has a significant effect on the selectivity of insertion of functionalised fullerenes into SWNTs.

Original language	English
Pages (from-to)	969-974
Number of pages	6
Journal	Materials Science and Technology
Volume	20
Issue number	8
DOIs	https://doi.org/10.1179/174328413X13789824293425
Publication status	Published - Aug 2004
Externally published	Yes

Keywords

Carbon nanotubes
Fullerenes
Hydrogen bonding
Self-assembly
Van der Waals interactions

Access to Document

10.1179/174328413X13789824293425

Cite this

Khlobystov, A. N., Porfyrakis, K., Britz, D. A., Kanai, M., Scipioni, R., Lyapin, S. G., Wiltshire, J. G., Ardavan, A., Nguyen-Manh, D., Nicholas, R. J., Pettifor, D. G., Dennis, T. J. S., & Briggs, G. A. D. (2004). Ordering and interaction of molecules encapsulated in carbon nanotubes. Materials Science and Technology, 20(8), 969-974. https://doi.org/10.1179/174328413X13789824293425

@article{79a02aac48d54540b286ffb27aa62499,

title = "Ordering and interaction of molecules encapsulated in carbon nanotubes",

abstract = "A clear understanding of the interactions between the building blocks of self-assembled molecular materials is essential for rational design of functional nanostructures. Intermolecular interactions have been investigated for three different classes of fullerenes in single-walled carbon nanotubes (SWNTs); van der Waals molecule - molecule and molecule - SWNT interactions control the geometry of the molecular arrays inside nanotubes; electrostatic intermolecular forces influence the alignment of polar endohedral fullerenes M@C82; and hydrogen bonding between functionalised fullerenes has a significant effect on the selectivity of insertion of functionalised fullerenes into SWNTs.",

keywords = "Carbon nanotubes, Fullerenes, Hydrogen bonding, Self-assembly, Van der Waals interactions",

author = "Khlobystov, \{A. N.\} and K. Porfyrakis and Britz, \{D. A.\} and M. Kanai and R. Scipioni and Lyapin, \{S. G.\} and Wiltshire, \{J. G.\} and A. Ardavan and D. Nguyen-Manh and Nicholas, \{R. J.\} and Pettifor, \{D. G.\} and Dennis, \{T. J.S.\} and Briggs, \{G. A.D.\}",

year = "2004",

month = aug,

doi = "10.1179/174328413X13789824293425",

language = "English",

volume = "20",

pages = "969--974",

journal = "Materials Science and Technology",

issn = "0267-0836",

number = "8",

}

TY - JOUR

T1 - Ordering and interaction of molecules encapsulated in carbon nanotubes

AU - Khlobystov, A. N.

AU - Porfyrakis, K.

AU - Britz, D. A.

AU - Kanai, M.

AU - Scipioni, R.

AU - Lyapin, S. G.

AU - Wiltshire, J. G.

AU - Ardavan, A.

AU - Nguyen-Manh, D.

AU - Nicholas, R. J.

AU - Pettifor, D. G.

AU - Dennis, T. J.S.

AU - Briggs, G. A.D.

PY - 2004/8

Y1 - 2004/8

N2 - A clear understanding of the interactions between the building blocks of self-assembled molecular materials is essential for rational design of functional nanostructures. Intermolecular interactions have been investigated for three different classes of fullerenes in single-walled carbon nanotubes (SWNTs); van der Waals molecule - molecule and molecule - SWNT interactions control the geometry of the molecular arrays inside nanotubes; electrostatic intermolecular forces influence the alignment of polar endohedral fullerenes M@C82; and hydrogen bonding between functionalised fullerenes has a significant effect on the selectivity of insertion of functionalised fullerenes into SWNTs.

AB - A clear understanding of the interactions between the building blocks of self-assembled molecular materials is essential for rational design of functional nanostructures. Intermolecular interactions have been investigated for three different classes of fullerenes in single-walled carbon nanotubes (SWNTs); van der Waals molecule - molecule and molecule - SWNT interactions control the geometry of the molecular arrays inside nanotubes; electrostatic intermolecular forces influence the alignment of polar endohedral fullerenes M@C82; and hydrogen bonding between functionalised fullerenes has a significant effect on the selectivity of insertion of functionalised fullerenes into SWNTs.

KW - Carbon nanotubes

KW - Fullerenes

KW - Hydrogen bonding

KW - Self-assembly

KW - Van der Waals interactions

UR - https://www.scopus.com/pages/publications/4344633711

U2 - 10.1179/174328413X13789824293425

DO - 10.1179/174328413X13789824293425

M3 - Article

AN - SCOPUS:4344633711

SN - 0267-0836

VL - 20

SP - 969

EP - 974

JO - Materials Science and Technology

JF - Materials Science and Technology

IS - 8

ER -

Ordering and interaction of molecules encapsulated in carbon nanotubes

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this