Molecular motion of endohedral fullerenes in single-walled carbon nanotubes

Andrei N. Khlobystov; Kyriakos Porfyrakis; Mito Kanai; David A. Britz; Arzhang Ardavan; Hisanori Shinohara; T. John S. Dennis; G. Andrew D. Briggs

doi:10.1002/anie.200352389

Molecular motion of endohedral fullerenes in single-walled carbon nanotubes

Andrei N. Khlobystov^*
, Kyriakos Porfyrakis
, Mito Kanai
, David A. Britz
, Arzhang Ardavan
, Hisanori Shinohara
, T. John S. Dennis
, G. Andrew D. Briggs

^*Corresponding author for this work

University of Oxford
Queen Mary University of London
Nagoya University

Research output: Contribution to journal › Article › peer-review

68 Citations (Scopus)

Abstract

Rock and roll: Endohedral fullerenes Ce@C₈₂ inserted in single-walled carbon nanotubes (SWNTs) interact by electrostatic interactions and exhibit unusual dynamic behavior. Translational oscillations and discontinuous molecular rotations are observed (by high-resolution transmission electron microscopy) for the first time for molecular arrays inside SWNTs (see picture; blue dot=endohedral Ce atom). The fullerene rotation rate is different for isolated and aggregated nanotubes.

Original language	English
Pages (from-to)	1386-1389
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	43
Issue number	11
DOIs	https://doi.org/10.1002/anie.200352389
Publication status	Published - 5 Mar 2004
Externally published	Yes

Keywords

Carbon nanotubes
Cerium
Electron microscopy
Fullerenes

Access to Document

10.1002/anie.200352389

Cite this

@article{c9623661ce104e1fa0dc60d3655e4682,

title = "Molecular motion of endohedral fullerenes in single-walled carbon nanotubes",

abstract = "Rock and roll: Endohedral fullerenes Ce@C82 inserted in single-walled carbon nanotubes (SWNTs) interact by electrostatic interactions and exhibit unusual dynamic behavior. Translational oscillations and discontinuous molecular rotations are observed (by high-resolution transmission electron microscopy) for the first time for molecular arrays inside SWNTs (see picture; blue dot=endohedral Ce atom). The fullerene rotation rate is different for isolated and aggregated nanotubes.",

keywords = "Carbon nanotubes, Cerium, Electron microscopy, Fullerenes",

author = "Khlobystov, \{Andrei N.\} and Kyriakos Porfyrakis and Mito Kanai and Britz, \{David A.\} and Arzhang Ardavan and Hisanori Shinohara and Dennis, \{T. John S.\} and Briggs, \{G. Andrew D.\}",

year = "2004",

month = mar,

day = "5",

doi = "10.1002/anie.200352389",

language = "English",

volume = "43",

pages = "1386--1389",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley \& Sons, Ltd",

number = "11",

}

TY - JOUR

T1 - Molecular motion of endohedral fullerenes in single-walled carbon nanotubes

AU - Khlobystov, Andrei N.

AU - Porfyrakis, Kyriakos

AU - Kanai, Mito

AU - Britz, David A.

AU - Ardavan, Arzhang

AU - Shinohara, Hisanori

AU - Dennis, T. John S.

AU - Briggs, G. Andrew D.

PY - 2004/3/5

Y1 - 2004/3/5

N2 - Rock and roll: Endohedral fullerenes Ce@C82 inserted in single-walled carbon nanotubes (SWNTs) interact by electrostatic interactions and exhibit unusual dynamic behavior. Translational oscillations and discontinuous molecular rotations are observed (by high-resolution transmission electron microscopy) for the first time for molecular arrays inside SWNTs (see picture; blue dot=endohedral Ce atom). The fullerene rotation rate is different for isolated and aggregated nanotubes.

AB - Rock and roll: Endohedral fullerenes Ce@C82 inserted in single-walled carbon nanotubes (SWNTs) interact by electrostatic interactions and exhibit unusual dynamic behavior. Translational oscillations and discontinuous molecular rotations are observed (by high-resolution transmission electron microscopy) for the first time for molecular arrays inside SWNTs (see picture; blue dot=endohedral Ce atom). The fullerene rotation rate is different for isolated and aggregated nanotubes.

KW - Carbon nanotubes

KW - Cerium

KW - Electron microscopy

KW - Fullerenes

UR - https://www.scopus.com/pages/publications/4544314721

U2 - 10.1002/anie.200352389

DO - 10.1002/anie.200352389

M3 - Article

AN - SCOPUS:4544314721

SN - 1433-7851

VL - 43

SP - 1386

EP - 1389

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 11

ER -

Molecular motion of endohedral fullerenes in single-walled carbon nanotubes

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this