Formation of an heterochiral supramolecular cage by diastereomer self-discrimination: Fluorescence enhancement and C60 sensing

Carlos Solano Arribas; Ola F. Wendt; Anders P. Sundin; Carl Johan Carling; Ruiyao Wang; Robert P. Lemieux; Kenneth Wärnmark

doi:10.1039/b927030b

Formation of an heterochiral supramolecular cage by diastereomer self-discrimination: Fluorescence enhancement and C₆₀ sensing

Carlos Solano Arribas
, Ola F. Wendt
, Anders P. Sundin
, Carl Johan Carling
, Ruiyao Wang
, Robert P. Lemieux
, Kenneth Wärnmark^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

30 Citations (Scopus)

Abstract

Diastereomer discrimination was observed in the formation of a metallomacrocycle from a racemic ligand based on Tröger's base. The metallomacrocycle exhibited a dramatic increase in fluorescence intensity compared to the ligand and its fluorescence was efficiently quenched by C ₆₀.

Original language	English
Pages (from-to)	4381-4383
Number of pages	3
Journal	Chemical Communications
Volume	46
Issue number	24
DOIs	https://doi.org/10.1039/b927030b
Publication status	Published - 2010
Externally published	Yes

Access to Document

10.1039/b927030b

Cite this

@article{bdddded741e940c9adc7f224ea7a9b2e,

title = "Formation of an heterochiral supramolecular cage by diastereomer self-discrimination: Fluorescence enhancement and C60 sensing",

abstract = "Diastereomer discrimination was observed in the formation of a metallomacrocycle from a racemic ligand based on Tr{\"o}ger's base. The metallomacrocycle exhibited a dramatic increase in fluorescence intensity compared to the ligand and its fluorescence was efficiently quenched by C 60.",

author = "Arribas, \{Carlos Solano\} and Wendt, \{Ola F.\} and Sundin, \{Anders P.\} and Carling, \{Carl Johan\} and Ruiyao Wang and Lemieux, \{Robert P.\} and Kenneth W{\"a}rnmark",

year = "2010",

doi = "10.1039/b927030b",

language = "English",

volume = "46",

pages = "4381--4383",

journal = "Chemical Communications",

issn = "1359-7345",

number = "24",

}

TY - JOUR

T1 - Formation of an heterochiral supramolecular cage by diastereomer self-discrimination

T2 - Fluorescence enhancement and C60 sensing

AU - Arribas, Carlos Solano

AU - Wendt, Ola F.

AU - Sundin, Anders P.

AU - Carling, Carl Johan

AU - Wang, Ruiyao

AU - Lemieux, Robert P.

AU - Wärnmark, Kenneth

PY - 2010

Y1 - 2010

N2 - Diastereomer discrimination was observed in the formation of a metallomacrocycle from a racemic ligand based on Tröger's base. The metallomacrocycle exhibited a dramatic increase in fluorescence intensity compared to the ligand and its fluorescence was efficiently quenched by C 60.

AB - Diastereomer discrimination was observed in the formation of a metallomacrocycle from a racemic ligand based on Tröger's base. The metallomacrocycle exhibited a dramatic increase in fluorescence intensity compared to the ligand and its fluorescence was efficiently quenched by C 60.

UR - https://www.scopus.com/pages/publications/77953307037

U2 - 10.1039/b927030b

DO - 10.1039/b927030b

M3 - Article

C2 - 20473442

AN - SCOPUS:77953307037

SN - 1359-7345

VL - 46

SP - 4381

EP - 4383

JO - Chemical Communications

JF - Chemical Communications

IS - 24

ER -

Formation of an heterochiral supramolecular cage by diastereomer self-discrimination: Fluorescence enhancement and C60 sensing

Abstract

Access to Document

Other files and links

Cite this

Formation of an heterochiral supramolecular cage by diastereomer self-discrimination: Fluorescence enhancement and C₆₀ sensing