Encapsulation of FePt and FePt3 alloys inside carbon-foam materials

Filippo S. Boi; Jiayu Wang; Yi He; Jiqiu Wen; Shanling Wang; Xi Zhang; Tian Yu; Lin Shi; Qiuyan Ma; Mu Lan; Li Lei; Gang Xiang

doi:10.1088/2053-1591/ab0edf

Encapsulation of FePt and FePt₃ alloys inside carbon-foam materials

Filippo S. Boi^*, Jiayu Wang, Yi He, Jiqiu Wen, Shanling Wang, Xi Zhang, Tian Yu, Lin Shi, Qiuyan Ma, Mu Lan, Li Lei, Gang Xiang

^*Corresponding author for this work

Sichuan University

Research output: Contribution to journal › Article › peer-review

Abstract

We demonstrate an advanced chemical vapour deposition (CVD) approach in which the addition of Pt-containing hydrocarbons to ferrocene allows the nucleation of a novel carbon-foam material completely filled with elemental Fe and Pt crystal-phases. These phases are then found to alloy into tetragonal FePt and cubic FePt₃ in specific annealing conditions. A dependence of the FePt nucleation on the Ar/H₂ flow rate is reported. In addition, high pressure (5 GPa) experiments are found to favor the formation of a single FePt₃ encapsulated phase together with the nucleation of C-O rich carbon layers in the foam surface.

Original language	English
Article number	065613
Journal	Materials Research Express
Volume	6
Issue number	6
DOIs	https://doi.org/10.1088/2053-1591/ab0edf
Publication status	Published - 27 Mar 2019
Externally published	Yes

Keywords

carbon foam
FePt
FePt

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10.1088/2053-1591/ab0edf

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title = "Encapsulation of FePt and FePt3 alloys inside carbon-foam materials",

abstract = "We demonstrate an advanced chemical vapour deposition (CVD) approach in which the addition of Pt-containing hydrocarbons to ferrocene allows the nucleation of a novel carbon-foam material completely filled with elemental Fe and Pt crystal-phases. These phases are then found to alloy into tetragonal FePt and cubic FePt3 in specific annealing conditions. A dependence of the FePt nucleation on the Ar/H2 flow rate is reported. In addition, high pressure (5 GPa) experiments are found to favor the formation of a single FePt3 encapsulated phase together with the nucleation of C-O rich carbon layers in the foam surface.",

keywords = "carbon foam, FePt, FePt",

author = "Boi, \{Filippo S.\} and Jiayu Wang and Yi He and Jiqiu Wen and Shanling Wang and Xi Zhang and Tian Yu and Lin Shi and Qiuyan Ma and Mu Lan and Li Lei and Gang Xiang",

note = "Publisher Copyright: {\textcopyright} 2019 IOP Publishing Ltd.",

year = "2019",

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day = "27",

doi = "10.1088/2053-1591/ab0edf",

language = "English",

volume = "6",

journal = "Materials Research Express",

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TY - JOUR

T1 - Encapsulation of FePt and FePt3 alloys inside carbon-foam materials

AU - Boi, Filippo S.

AU - Wang, Jiayu

AU - He, Yi

AU - Wen, Jiqiu

AU - Wang, Shanling

AU - Zhang, Xi

AU - Yu, Tian

AU - Shi, Lin

AU - Ma, Qiuyan

AU - Lan, Mu

AU - Lei, Li

AU - Xiang, Gang

PY - 2019/3/27

Y1 - 2019/3/27

N2 - We demonstrate an advanced chemical vapour deposition (CVD) approach in which the addition of Pt-containing hydrocarbons to ferrocene allows the nucleation of a novel carbon-foam material completely filled with elemental Fe and Pt crystal-phases. These phases are then found to alloy into tetragonal FePt and cubic FePt3 in specific annealing conditions. A dependence of the FePt nucleation on the Ar/H2 flow rate is reported. In addition, high pressure (5 GPa) experiments are found to favor the formation of a single FePt3 encapsulated phase together with the nucleation of C-O rich carbon layers in the foam surface.

AB - We demonstrate an advanced chemical vapour deposition (CVD) approach in which the addition of Pt-containing hydrocarbons to ferrocene allows the nucleation of a novel carbon-foam material completely filled with elemental Fe and Pt crystal-phases. These phases are then found to alloy into tetragonal FePt and cubic FePt3 in specific annealing conditions. A dependence of the FePt nucleation on the Ar/H2 flow rate is reported. In addition, high pressure (5 GPa) experiments are found to favor the formation of a single FePt3 encapsulated phase together with the nucleation of C-O rich carbon layers in the foam surface.

KW - carbon foam

KW - FePt

UR - https://www.scopus.com/pages/publications/85064461582

U2 - 10.1088/2053-1591/ab0edf

DO - 10.1088/2053-1591/ab0edf

M3 - Article

AN - SCOPUS:85064461582

SN - 2053-1591

VL - 6

JO - Materials Research Express

JF - Materials Research Express

IS - 6

M1 - 065613

ER -

Encapsulation of FePt and FePt₃ alloys inside carbon-foam materials

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