{Bis[2-(diphenyl-phosphan-yl)eth-yl]phenyl-phosphane-κ 3 P,P′,P′′}[(Z)-8-mesityl-cyclo-oct-4-en-1-yl]platinum(II) tetra-fluorido-borate dichloro-methane disolvate

Shu Bin Zhao; Rui Yao Wang; Michel R. Gagné

doi:10.1107/S1600536811023853

{Bis[2-(diphenyl-phosphan-yl)eth-yl]phenyl-phosphane-κ ³ P,P′,P′′}[(Z)-8-mesityl-cyclo-oct-4-en-1-yl]platinum(II) tetra-fluorido-borate dichloro-methane disolvate

Shu Bin Zhao^*
, Rui Yao Wang
, Michel R. Gagné

^*Corresponding author for this work

University of North Carolina at Chapel Hill
Queen's University Kingston

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

In the title ionic compound, [Pt(C ₁₇H ₂₃)(C ₃₄H ₃₃P ₃)](BF ₄)· ₂CH ₂C _l2, the Pt ^II atom adopts a square-planar coordination geometry with the large (Z)-8-mesityl-cyclo-oct-4-en- 1-yl group occupying the fourth coordination site. The (triphos)Pt moiety and the mesityl group are attached to the cyclo-oct-4-ene motif at the 1- and 8-position in a syn configuration. The (BF4) ^- anion and one of the dichloromethane solvate molecules each are disordered over two sets of sites.

Original language	English
Pages (from-to)	m972
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	67
Issue number	7
DOIs	https://doi.org/10.1107/S1600536811023853
Publication status	Published - Jul 2011
Externally published	Yes

Access to Document

10.1107/S1600536811023853

Cite this

@article{acb86d29b6e54de7a52343e7ec1a4134,

title = "\{Bis[2-(diphenyl-phosphan-yl)eth-yl]phenyl-phosphane-κ 3 P,P′,P′′\}[(Z)-8-mesityl-cyclo-oct-4-en-1-yl]platinum(II) tetra-fluorido-borate dichloro-methane disolvate",

abstract = "In the title ionic compound, [Pt(C 17H 23)(C 34H 33P 3)](BF 4)· 2CH 2C l2, the Pt II atom adopts a square-planar coordination geometry with the large (Z)-8-mesityl-cyclo-oct-4-en- 1-yl group occupying the fourth coordination site. The (triphos)Pt moiety and the mesityl group are attached to the cyclo-oct-4-ene motif at the 1- and 8-position in a syn configuration. The (BF4) - anion and one of the dichloromethane solvate molecules each are disordered over two sets of sites.",

author = "Zhao, \{Shu Bin\} and Wang, \{Rui Yao\} and Gagn{\'e}, \{Michel R.\}",

year = "2011",

month = jul,

doi = "10.1107/S1600536811023853",

language = "English",

volume = "67",

pages = "m972",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

number = "7",

}

{Bis[2-(diphenyl-phosphan-yl)eth-yl]phenyl-phosphane-κ ³ P,P′,P′′}[(Z)-8-mesityl-cyclo-oct-4-en-1-yl]platinum(II) tetra-fluorido-borate dichloro-methane disolvate. / Zhao, Shu Bin; Wang, Rui Yao; Gagné, Michel R.
In: Acta Crystallographica Section E: Structure Reports Online, Vol. 67, No. 7, 07.2011, p. m972.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - {Bis[2-(diphenyl-phosphan-yl)eth-yl]phenyl-phosphane-κ 3 P,P′,P′′}[(Z)-8-mesityl-cyclo-oct-4-en-1-yl]platinum(II) tetra-fluorido-borate dichloro-methane disolvate

AU - Zhao, Shu Bin

AU - Wang, Rui Yao

AU - Gagné, Michel R.

PY - 2011/7

Y1 - 2011/7

N2 - In the title ionic compound, [Pt(C 17H 23)(C 34H 33P 3)](BF 4)· 2CH 2C l2, the Pt II atom adopts a square-planar coordination geometry with the large (Z)-8-mesityl-cyclo-oct-4-en- 1-yl group occupying the fourth coordination site. The (triphos)Pt moiety and the mesityl group are attached to the cyclo-oct-4-ene motif at the 1- and 8-position in a syn configuration. The (BF4) - anion and one of the dichloromethane solvate molecules each are disordered over two sets of sites.

AB - In the title ionic compound, [Pt(C 17H 23)(C 34H 33P 3)](BF 4)· 2CH 2C l2, the Pt II atom adopts a square-planar coordination geometry with the large (Z)-8-mesityl-cyclo-oct-4-en- 1-yl group occupying the fourth coordination site. The (triphos)Pt moiety and the mesityl group are attached to the cyclo-oct-4-ene motif at the 1- and 8-position in a syn configuration. The (BF4) - anion and one of the dichloromethane solvate molecules each are disordered over two sets of sites.

UR - https://www.scopus.com/pages/publications/79960036386

U2 - 10.1107/S1600536811023853

DO - 10.1107/S1600536811023853

M3 - Article

AN - SCOPUS:79960036386

SN - 1600-5368

VL - 67

SP - m972

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 7

ER -

{Bis[2-(diphenyl-phosphan-yl)eth-yl]phenyl-phosphane-κ ³ P,P′,P′′}[(Z)-8-mesityl-cyclo-oct-4-en-1-yl]platinum(II) tetra-fluorido-borate dichloro-methane disolvate

Abstract

Access to Document

Other files and links

Fingerprint

Cite this