TY - JOUR
T1 - {Bis[2-(diphenyl-phosphan-yl)eth-yl]phenyl-phosphane-κ 3 P,P′,P′′}[(Z)-8-mesityl-cyclo-oct-4-en-1-yl]platinum(II) tetra-fluorido-borate dichloro-methane disolvate
AU - Zhao, Shu Bin
AU - Wang, Rui Yao
AU - Gagné, Michel R.
PY - 2011/7
Y1 - 2011/7
N2 - In the title ionic compound, [Pt(C 17H 23)(C 34H 33P 3)](BF 4)· 2CH 2C l2, the Pt II atom adopts a square-planar coordination geometry with the large (Z)-8-mesityl-cyclo-oct-4-en- 1-yl group occupying the fourth coordination site. The (triphos)Pt moiety and the mesityl group are attached to the cyclo-oct-4-ene motif at the 1- and 8-position in a syn configuration. The (BF4) - anion and one of the dichloromethane solvate molecules each are disordered over two sets of sites.
AB - In the title ionic compound, [Pt(C 17H 23)(C 34H 33P 3)](BF 4)· 2CH 2C l2, the Pt II atom adopts a square-planar coordination geometry with the large (Z)-8-mesityl-cyclo-oct-4-en- 1-yl group occupying the fourth coordination site. The (triphos)Pt moiety and the mesityl group are attached to the cyclo-oct-4-ene motif at the 1- and 8-position in a syn configuration. The (BF4) - anion and one of the dichloromethane solvate molecules each are disordered over two sets of sites.
UR - https://www.scopus.com/pages/publications/79960036386
U2 - 10.1107/S1600536811023853
DO - 10.1107/S1600536811023853
M3 - Article
AN - SCOPUS:79960036386
SN - 1600-5368
VL - 67
SP - m972
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 7
ER -