A quantitative UV-VIS probe of enantioselectivity in metalloporphyrin catalyzed oxygenation using aluminium model complexes

James P. Collman; Zhong Wang; Christian Linde; Lei Fu; Louis Dang; John I. Brauman

doi:10.1039/a904141i

A quantitative UV-VIS probe of enantioselectivity in metalloporphyrin catalyzed oxygenation using aluminium model complexes

James P. Collman^*, Zhong Wang, Christian Linde, Lei Fu, Louis Dang, John I. Brauman

^*Corresponding author for this work

Stanford University

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

UV-VIS spectroscopy is used to study the selective binding of enantiomeric pairs of chiral epoxides to an ααββ binaphthyl-strapped A1 porphyrin; the binding selectivity correlates to the enantioselectivity in the epoxidation of alkenes catalyzed by its Fe analog.

Original language	English
Pages (from-to)	1783-1784
Number of pages	2
Journal	Chemical Communications
Issue number	18
DOIs	https://doi.org/10.1039/a904141i
Publication status	Published - 21 Sept 1999
Externally published	Yes

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title = "A quantitative UV-VIS probe of enantioselectivity in metalloporphyrin catalyzed oxygenation using aluminium model complexes",

abstract = "UV-VIS spectroscopy is used to study the selective binding of enantiomeric pairs of chiral epoxides to an ααββ binaphthyl-strapped A1 porphyrin; the binding selectivity correlates to the enantioselectivity in the epoxidation of alkenes catalyzed by its Fe analog.",

author = "Collman, \{James P.\} and Zhong Wang and Christian Linde and Lei Fu and Louis Dang and Brauman, \{John I.\}",

year = "1999",

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doi = "10.1039/a904141i",

language = "English",

pages = "1783--1784",

journal = "Chemical Communications",

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TY - JOUR

T1 - A quantitative UV-VIS probe of enantioselectivity in metalloporphyrin catalyzed oxygenation using aluminium model complexes

AU - Collman, James P.

AU - Wang, Zhong

AU - Linde, Christian

AU - Fu, Lei

AU - Dang, Louis

AU - Brauman, John I.

PY - 1999/9/21

Y1 - 1999/9/21

N2 - UV-VIS spectroscopy is used to study the selective binding of enantiomeric pairs of chiral epoxides to an ααββ binaphthyl-strapped A1 porphyrin; the binding selectivity correlates to the enantioselectivity in the epoxidation of alkenes catalyzed by its Fe analog.

AB - UV-VIS spectroscopy is used to study the selective binding of enantiomeric pairs of chiral epoxides to an ααββ binaphthyl-strapped A1 porphyrin; the binding selectivity correlates to the enantioselectivity in the epoxidation of alkenes catalyzed by its Fe analog.

UR - https://www.scopus.com/pages/publications/0033592381

U2 - 10.1039/a904141i

DO - 10.1039/a904141i

M3 - Article

AN - SCOPUS:0033592381

SN - 1359-7345

SP - 1783

EP - 1784

JO - Chemical Communications

JF - Chemical Communications

IS - 18

ER -

A quantitative UV-VIS probe of enantioselectivity in metalloporphyrin catalyzed oxygenation using aluminium model complexes

Abstract

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